Citation: Wang Xin-Rui, Li Yong, Tang Li-Ping, Gan Wen, Zhou Wei, Zhao Yu-Fei, Bai Dong-Sheng. Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti⁴⁺ and its application as UV absorbent[J]. Chinese Chemical Letters, ;2017, 28(2): 394-399. doi: 10.1016/j.cclet.2016.09.002 shu

Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti⁴⁺ and its application as UV absorbent

a.
Beijing Key Lab of Plant Resource Research and Development/Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China
b.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Wang Xin-Rui, wangxinrui@th.btbu.edu.cn
Received Date: 4 July 2016
Revised Date: 13 August 2016
Accepted Date: 29 August 2016
Available Online: 12 February 2016

Figures(8)

ZnTi-layered double hydroxides (LDHs) with varying Zn/Ti ratio have been synthesized by coprecipitation of zinc and titanium salts from homogeneous solution. The obtained ZnTi-LDHs possess high crystallinity and hierarchical structure with improved UV-absorbance property. The UV-vis spectra show that the UV absorbing properties of ZnTi-LDHs is stronger and broader than both MgAl-LDH and ZnAl-LDH due to the existence of Ti. Moreover, the UV absorption property increased with the content of Ti, which can be ascribed to the decrease in the band gap energy, as clearly confirmed by density functional theory calculations. When irradiated by UV rays, the property of the samples with generated free radicals (OH^· and O₂^·-) was evaluated by means of electron spin resonance (EPR). ZnTi-LDHs generated a relatively lower active radicals in contrast with TiO₂ and ZnO, which implied an increased safety used as sunscreens. Therefore, this work provides a detailed understanding of UV shielding properties of ZnTiLDHs which was unrevealed previously, and demonstrates the expansive application prospects of ZnTiLDHs in the field of sunscreens.
- Layered double hydroxide,
- UV absorbent,
- Density functional theory calculations,
- Photoactivity,
- Band gap
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti4+ and its application as UV absorbent

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通讯作者: 陈斌, bchen63@163.com

Fabrication of Zn-Ti layered double hydroxide by varying cationic ratio of Ti⁴⁺ and its application as UV absorbent