Citation: Liu Zun-Qi, Liu Yang, Chen Yuan, Zhao Wu-Qiang, Fang Wei-Na. Synthesis, characterization, and phase transition of an inorganic-organic hybrid compound, [(3-nitroanilinium⁺) (18-crown-6)] [IO₄^-](CH₃OH)[J]. Chinese Chemical Letters, ;2017, 28(2): 297-301. doi: 10.1016/j.cclet.2016.07.013 shu

Synthesis, characterization, and phase transition of an inorganic-organic hybrid compound, [(3-nitroanilinium⁺) (18-crown-6)] [IO₄^-](CH₃OH)

Chemical Engineering College, Xinjiang Agricultural University, Urumqi 830052, China

Corresponding author: Liu Zun-Qi, zunqi85@163.com
Received Date: 11 June 2016
Revised Date: 21 June 2016
Accepted Date: 4 July 2016
Available Online: 18 February 2016

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A novel inorganic-organic hybrid supramolecular compound, [(3-nitroanilinium⁺)(18-crown-6)] [IO₄^-](CH₃OH) (1), was discovered as phase-transition materials displaying dielectric anomalous behaviors. The yellow block crystal formed by N-H…O hydrogen bonding that made contact through the cavity of 18-crown-6 was characterized by single-crystal X-ray diffraction, elemental analysis, infrared analysis, thermogravimetric analysis, differential scanning calorimetry, and potential-energy calculations. Differential scanning calorimetry measurements indicate that the compound experiences a reversible phase transition at around 220 K. Temperature-dependent dielectric measurements further confirm the phase transitions. Potential-energy calculations demonstrate that the phase transition occurs due to the molecular order-disorder rotation of CH₃OH, whereas the space grouping of the crystal remains unchanged.
- Phase transition,
- Crystal structure,
- Molecular rotation,
- Dielectric anomaly
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, characterization, and phase transition of an inorganic-organic hybrid compound, [(3-nitroanilinium+) (18-crown-6)] [IO4-](CH3OH)

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通讯作者: 陈斌, bchen63@163.com

Synthesis, characterization, and phase transition of an inorganic-organic hybrid compound, [(3-nitroanilinium⁺) (18-crown-6)] [IO₄^-](CH₃OH)