Citation: Paul Bappi, Vadivel Sethumathavan, Sankar Dhar Siddhartha. α-Fe₂O₃ immobilized benzimidazolium tribromide as novel magnetically retrievable catalyst for one-pot synthesis of highly functionalized piperidines[J]. Chinese Chemical Letters, ;2016, 27(11): 1725-1730. doi: 10.1016/j.cclet.2016.07.005 shu

α-Fe₂O₃ immobilized benzimidazolium tribromide as novel magnetically retrievable catalyst for one-pot synthesis of highly functionalized piperidines

a.
Department of Chemistry, National Institute of Technology Silchar, Silchar-788010, Assam, India
b.
Department of Chemistry, PSG College of Technology, Peelamedu, Coimbatore-641004, Tamilnadu, India

Corresponding author: Paul Bappi, bappipaulnits@gmail.com Sankar Dhar Siddhartha, ssd_iitg@hotmail.com
Received Date: 11 May 2016
Revised Date: 27 June 2016
Accepted Date: 4 July 2016
Available Online: 21 November 2016

Figures(7)

Nanostructured α-Fe₂O₃ were prepared by precipitation followed by calcination method.Cetyltrimethylammonium bromide (CTAB) was used as surfactant.The nano α-Fe₂O₃ was then silanized with (3-chloropropyl)-triethoxysilane (CPTES) by room temperature mixing of α-Fe₂O₃ and CPTES to produce silane coated α-Fe₂O₃(ClPr-Si@Fe₂O₃).As-synthesized ClPr-Si@Fe₂O₃ was functionalized via covalent grafting of benzimidazole to produce 3-(1-benzimidazole) Pr-Si@Fe₂O₃.This was further reacted with bromine to afford α-Fe₂O₃ immobilized benzimidazolium tribromide (α-Fe₂O₃-BIM tribromide).This ionic liquid (IL) α-Fe₂O₃ BIM tribromide was characterized by FT-IR, XRD, TEM, SEM, TGA, VSM, EDX and BET analysis.The as-synthesized IL tribromide was used as catalyst for one-pot synthesis of highly substituted piperidines.The method is greener in terms of solvent selection, recovery of the catalyst and efficiency.
- Nano α-Fe₂O₃,
- Covalent grafting,
- Ionic liquid,
- Multicomponent reaction
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

α-Fe2O3 immobilized benzimidazolium tribromide as novel magnetically retrievable catalyst for one-pot synthesis of highly functionalized piperidines

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通讯作者: 陈斌, bchen63@163.com

α-Fe₂O₃ immobilized benzimidazolium tribromide as novel magnetically retrievable catalyst for one-pot synthesis of highly functionalized piperidines