Citation: Deng Chuan-Dong, Qiao Yu-Jia, Chen Qing-De, Shen Xing-Hai. Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)[J]. Chinese Chemical Letters, ;2017, 28(1): 19-23. doi: 10.1016/j.cclet.2016.06.020 shu

Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)

Beijing National Laboratory for Molecular Sciences (BNLMS), Fundamental Science on Radiochemistry and Radiation Chemistry Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Shen Xing-Hai, xshen@pku.edu.cn
Received Date: 11 May 2016
Revised Date: 31 May 2016
Accepted Date: 6 June 2016
Available Online: 21 January 2016

Figures(7)

Two single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd) were prepared and characterized by element analysis, single crystal X-ray diffraction, PXRD, FT-IR, TGA and fluorescence spectroscopy. The two compounds have similar coordinate structures, in which the central metal ion is coordinated by four TBPO (Tri-n-butylphosphine oxide) molecules and two bidentate nitrates, while NTf₂^-(bis (trifluor-(bis (trifluoromethylsulfonyl) imide anion) acts as the counter anion. The packing modes of the two crystals are same. The two single crystals are the focus on 8-coordinate tetra-TRPO complexes (TRPO is Trialkyphosphine oxides).
- Tri-n-butylphosphine oxide,
- Europium,
- Gadolinium,
- Single crystal
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Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)