Citation: Wu Xuan, Gao Lei, Sun Junzhao, Hu Xiao-Yu, Wang Leyong. Stable pillar [5] arene-based pseudo [1] rotaxanes formed in polar solution[J]. Chinese Chemical Letters, ;2016, 27(11): 1655-1660. doi: 10.1016/j.cclet.2016.05.004 shu

Stable pillar [5] arene-based pseudo [1] rotaxanes formed in polar solution

Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Hu Xiao-Yu, huxy@nju.edu.cn
Received Date: 23 February 2016
Revised Date: 18 April 2016
Accepted Date: 28 April 2016
Available Online: 11 November 2016

Figures(13)

Mono-alkyl-functionalized pillar[5] arenes P1, P2, and P3 were synthesized by click reaction, which exhibited different self-assembly behavior in polar solvent DMSO.Stable pseudo [1] rotaxane was formed by the self-complexation from P1 or P2, whereas, concentration-dependent pseudorotaxane structures were generated by P3 which bearing more flexible side chain.Interestingly, the obtained pseudo[1]rotaxanes exhibited a dynamic fast assembly process upon adding NaBF₄, resulting in the formation of Na⁺-induced pseudorotaxanes.
- Pillar [5] arene,
- Pseudo [1] rotaxanes,
- Dynamic self-assembly,
- Na⁺-induced pseudorotaxanes,
- Polar solution
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