Citation: Yu Zhi-Wei, Gao Shu-Xi, Xu Kai, Zhang You-Xiong, Peng Jun, Chen Ming-Cai. Synthesis and characterization of silsesquioxane-cored star-shaped hybrid polymer via "grafting from" RAFT polymerization[J]. Chinese Chemical Letters, ;2016, 27(11): 1696-1700. doi: 10.1016/j.cclet.2016.04.018 shu

Synthesis and characterization of silsesquioxane-cored star-shaped hybrid polymer via "grafting from" RAFT polymerization

Yu Zhi-Wei ^a,b ,
Gao Shu-Xi ^a,b ,
Xu Kai ^a,b,, ,
Zhang You-Xiong ^a,b ,
Peng Jun ^a,b ,
Chen Ming-Cai ^a,b

a.
Key Laboratory of Polymer Material for Electronics, Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, China
b.
China University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Xu Kai, xk@gic.ac.cn
Received Date: 23 February 2016
Revised Date: 5 April 2016
Accepted Date: 14 April 2016
Available Online: 10 November 2016

Figures(4)

Organic/inorganic hybrid polymers have been widely studied for their potential use in nanocontainers and nanocarriers.In this article, one star-shaped hybrid polymer, polyhedral oligomeric silsesquioxane (POSS) grafted poly (N, N-(dimethylamino) ethyl methacrylate)(POSS-g-PDMA), was synthesized via reversible addition-fragmentation chain transfer polymerization (RAFT).The pH stimuli-responsive character of POSS-g-PDMA in aqueous solution were also studied.
- Star-polymer,
- RAFT,
- POSS,
- Graft from,
- Stimuli-responsive
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