Citation: Chao Xie, Qi-Meng Wu, Ruo-Ning Li, Gao-Chen Gu, Xue Zhang, Na Li, Richard Berndt, Jörg Kröger, Zi-Yong Shen, Shi-Min Hou, Yong-Feng Wang. Isolated supramolecules on surfaces studied with scanning tunneling microscopy[J]. Chinese Chemical Letters, ;2016, 27(6): 807-812. doi: 10.1016/j.cclet.2016.03.022 shu

Isolated supramolecules on surfaces studied with scanning tunneling microscopy

a Key Laboratory for the Physics and Chemistry of Nanodevices, Department of Electronics, Peking University, Beijing 100871, China;
b Department of Environmental Science, College of Environment and Resources, Jilin University, Changchun 130021, China;
c College of Electronic Science and Engineering, Jilin University, Changchun 130021, China;
d Institut für Experimentelle und Angewandte Physik, Christian-Albrechts-Universität zu Kiel, D-24098 Kiel, Germany;
e Institut für Physik, Technische Universität Ilmenau, D-98693 Ilmenau, Germany;
f Beida Information Research (BIR), Tianjin 300457, China

Received Date: 15 February 2016
Revised Date: 9 March 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 21522301, 21373020, 21403008, 61321001, 21433011, 61271050). the Ministry of Science and Technology (Nos. 2014CB239302 and 2013CB933404), and the Research Fund for the Doctoral Program of Higher Education (No. 20130001110029). R. B. acknowledges financial support from the Deutsche Forschungsgemeinschaft (DFG) via the SFB 677.

To date, supramolecular chemistry is an ever growing research field owing to its crucial role in molecular catalysis, recognition, medicine, data storage and processing as well as artificial photosynthetic devices. Different isolated supramolecules were prepared by molecular self-assembly on surfaces. This review mainly focuses on supramolecular aggregations on noble metal surfaces studied by scanning tunneling microscopy, including dimers, trimers, tetramers, pentamers, wire-like assemblies and Sierpin´ ski triangular fractals. The variety of self-assembled structures reflects the subtle balance between intermolecular and molecule-substrate interactions, which to some extent may be controlled by molecules, substrates and the molecular coverage. The comparative study of different architectures helps identifying the operative mechanisms that lead to the structural motifs. The application of these mechanisms may lead to novel assemblies with tailored physicochemical properties.
- Supramolecular aggregations,
- Scanning tunneling microscope (STM),
- Weak interactions,
- Self-assembly,
- Fractal,
- Sierpinski triangle
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