Citation: Ding Jian-Wei, Wang Rui. A new green system of HPW@MOFs catalyzed desulfurization using O₂ as oxidant[J]. Chinese Chemical Letters, ;2016, 27(5): 655-658. doi: 10.1016/j.cclet.2016.03.005 shu

A new green system of HPW@MOFs catalyzed desulfurization using O₂ as oxidant

Ding Jian-Wei ^a ,
Wang Rui ^b,,

a.
School of Environmental Science & Engineering, Shandong University, Jinan 250199, China
b.
Department of Environmental Science and Engineering, Shandong University, Jinan 250199, China

Corresponding author: Wang Rui, wangrui@sdu.edu.cn
Received Date: 24 January 2016
Revised Date: 29 February 2016
Accepted Date: 4 March 2016
Available Online: 12 May 2016

Figures(8)

A series of crystalline compounds were obtained from simple one-step hydrothermal reaction of copper nitrate, benzentricaboxylate and different Keggin polyoxometalates. Phosphotungstic acid immobilized in host matrix was selected for the first time as a recyclable and efficient catalyst in oxidative desulfurization process, under eco-sustainable conditions supported by the green oxidant O₂ and the green extracting agent distilled water. The efficiency of desulfurization with air was studied and it is possible to use air as green oxidant in desulfurization. Moreover, the catalyst is effective for the desulfurization of real diesel.
- Oxidative desulfurization,
- Metal organic frameworks,
- Oxygen,
- Real diesel,
- Recyclability
1. [1]
  Ma X.L., Sakanishi K., Mochida I.. Hydrodesulfurization reactivities of various sulfur compounds in diesel fuel[J]. Ind. Eng. Chem. Res., 1994,33:218-222.
2. [2]
  Zhang G.F., Wan R., Yu F.L., Zhao H.X.. Clean fuel-oriented investigation of thiophene oxidation by hydrogen peroxide using polyoxometalate as catalyst[J]. Chem. Pap., 2009,63:617-619.
3. [3]
  Zhang W., Zhang H., Xiao J.. Carbon nanotube catalysts for oxidative desulfurization of a model diesel fuel using molecular oxygen[J]. Green Chem., 2014,16:211-220.
4. [4]
  Wang J.L., Zhao D.S., Li K.X.. Oxidative desulfurization of dibenzothiophene using ozone and hydrogen peroxide in ionic liquid[J]. Energy Fuels, 2010,24:2527-2529.
5. [5]
  Nguyen L.T.L., Nguyen C.V., Dang G.H., Le K.K.A., Phan N.T.S.. Towards applications of metal-organic frameworks in catalysis:Friedel-Crafts acylation reaction over IRMOF-8 as an efficient heterogeneous catalyst[J]. J. Mol. Catal. A:Chem., 2011,349:28-35.
6. [6]
  Rowsell J.L.C., Yaghi O.M.. Strategies for hydrogen storage in metal-organic frameworks[J]. Angew. Chem. Int. Ed. Engl., 2005,44:4670-4679.
7. [7]
  Zhou X., Zhang Y., Yang X.G., Zhao L.Z., Wang G.Y.. Functionalized IRMOF-3 as efficient heterogeneous catalyst for the synthesis of cyclic carbonates[J]. J. Mol. Catal. A:Chem., 2012,361-362:12-16.
8. [8]
  Zhang L., Hu Y.H.. Desorption of dimethylformamide from Zn₄O(C₈H₄O₄)₃ framework[J]. Appl. Surf. Sci., 2011,257:3392-3398.
9. [9]
  Hu X.F., Lu Y.K., Dai F.N., Liu C.G., Liu Y.Q.. Host-guest synthesis and encapsulation of phosphotungstic acid in MIL-101 via "bottle around ship":an effective catalyst for oxidative desulfurization[J]. Microporous Mesoporous Mater., 2013,170:36-44.
10. [10]
  Rafiee E., Nobakht N.. Keggin type heteropoly acid, encapsulated in metal-organic framework:a heterogeneous and recyclable nanocatalyst for selective oxidation of sulfides and deep desulfurization of model fuels[J]. J. Mol. Catal. A:Chem., 2015,398:17-25.
11. [11]
  Ma X.L., Zhou A.N., Song C.S.. A novel method for oxidative desulfurization of liquid hydrocarbon fuels based on catalytic oxidation using molecular oxygen coupled with selective adsorption[J]. Catal. Today, 2007,123:276-284.
12. [12]
  Zhou X.R., Li J., Wang X.N., Jin K., Ma W.. Oxidative desulfurization of dibenzothiophene based on molecular oxygen and iron phthalocyanine[J]. Fuel Process. Technol., 2009,90:317-323.
13. [13]
  Sampanthar J.T., Xiao H., Dou J.. A novel oxidative desulfurization process to remove refractory sulfur compounds from diesel fuel[J]. Appl. Catal. B:Environ., 2006,63:85-93.
14. [14]
  Murata S., Murata K., Kidena K., Nomura M.. A novel oxidative desulfurization system for diesel fuels with molecular oxygen in the presence of cobalt catalysts and aldehydes[J]. Energy Fuels, 2004,18:116-121.
15. [15]
  Sun C.Y., Liu S.X., Liang D.D.. Highly stable crystalline catalysts based on a microporous metal-organic framework and polyoxometalates[J]. J. Am. Chem. Soc., 2009,131:1883-1888.
16. [16]
  Kozhevnikov I.V.. Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions[J]. Chem. Rev., 1998,98:171-198.
17. [17]
  Moffat J.B., McMonagle J.B., Taylor D.. Microporous heteropoly oxometalate heterogeneous catalysis[J]. Solid State Ionics, 1988,26:101-108.
18. [18]
  Deltcheff C.R., Fournier M., Franck R.. Vibrational investigations of polyoxometalates. 2. Evidence for anion-anion interactions in molybdenum(Ⅵ) and tungsten(Ⅵ) compounds related to the Keggin Structure[J]. Inorg. Chem., 1983,22:207-216.
19. [19]
  Cychosz K.A., Wong-Foy A.G., Matzger A.J.. Liquid phase adsorption by microporous coordination polymers:removal of organosulfur compounds[J]. J. Am. Chem. Soc., 2008,130:6938-6939.
20. [20]
  Khan N.A., Hasan Z., Jhung S.H.. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs):a review[J]. J. Hazard. Mater., 2013,244-245:444-456.
1. [1]
  Chaojian Xu , Juxin Yin , Sihong Wang , Yue Pan , Qianhe Zhang , Ningkang Xie , Shuo Yang , Shaowu Lv . Aerobic radical polymerization of hydrogels triggered by acetylacetone-transition metal self-initiation. Chinese Chemical Letters, 2025, 36(7): 111075-. doi: 10.1016/j.cclet.2025.111075
2. [2]
  Pin Cui , Ying Tang , Jie Yu , Zhen Yang , Shouhua Yang , Boqin Li , Gang Wang , Huan Pang , Feng Yu . Bimetallic ZnFe–NC prepared using microchannel reactor for oxygen reduction reaction and mechanism research. Chinese Chemical Letters, 2025, 36(9): 110303-. doi: 10.1016/j.cclet.2024.110303
3. [3]
  Cheng Cheng , Nasir Ali , Ji Liu , Juan Qiao , Ming Wang , Li Qi . Construction of degradable liposome-templated microporous metal-organic frameworks with commodious space for enzymes. Chinese Chemical Letters, 2024, 35(11): 109812-. doi: 10.1016/j.cclet.2024.109812
4. [4]
  Xinbao Tong , Jiaying Liu , Yanqi Zhao , Jingjun Li , Ye Tian , Qingyi Liu , Shuiying Gao , Rong Cao . Metal-organic framework supported carbon quantum dots as white light-emitting phosphor. Chinese Chemical Letters, 2025, 36(7): 111058-. doi: 10.1016/j.cclet.2025.111058
5. [5]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
6. [6]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
7. [7]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
8. [8]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
9. [9]
  Shaohua YANG , Na'na GAO , Yaqiong GONG . Metal-organic framework-templated construction of FeOOH@CoMoO₄/nickel foam heterostructure for enhanced oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2175-2185. doi: 10.11862/CJIC.20250218
10. [10]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661
11. [11]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
12. [12]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
13. [13]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
14. [14]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
15. [15]
  Guoying Han , Qazi Mohammad Junaid , Xiao Feng . Topology-driven directed synthesis of metal-organic frameworks. Chinese Journal of Structural Chemistry, 2025, 44(3): 100447-100447. doi: 10.1016/j.cjsc.2024.100447
16. [16]
  Chong-Chen Wang , Xiaohang Xu . Metal-organic frameworks helping resource and energy recovery from sludge. Chinese Chemical Letters, 2025, 36(10): 111287-. doi: 10.1016/j.cclet.2025.111287
17. [17]
  Qing Liu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Reactive oxygen species generation by organic materials for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(10): 111504-. doi: 10.1016/j.cclet.2025.111504
18. [18]
  Ziqin Li , Kai Hao , Longwei Xiang , Huayu Tian . Cationic covalent organic framework nanocarriers integrating both efficient gene silencing and real-time gene detection. Chinese Chemical Letters, 2025, 36(4): 109943-. doi: 10.1016/j.cclet.2024.109943
19. [19]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
20. [20]
  Cheng-Shuang Wang , Bing-Yu Zhou , Yi-Feng Wang , Cheng Yuan , Bo-Han Kou , Wei-Wei Zhao , Jing-Juan Xu . Bifunctional iron-porphyrin metal-organic frameworks for organic photoelectrochemical transistor gating and biosensing. Chinese Chemical Letters, 2025, 36(3): 110080-. doi: 10.1016/j.cclet.2024.110080

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1399)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A new green system of HPW@MOFs catalyzed desulfurization using O2 as oxidant

Metrics

通讯作者: 陈斌, bchen63@163.com

A new green system of HPW@MOFs catalyzed desulfurization using O₂ as oxidant