Citation: Dan-Ting Tan, Xu Shao, Shu-Feng Pang, Yun-Hong Zhang. The effect of CTAB on Na₂SO₄ nucleation in mixed Na₂SO₄/CTAB aerosols by FTIR-ATR technology[J]. Chinese Chemical Letters, ;2016, 27(7): 1073-1076. doi: 10.1016/j.cclet.2016.02.019 shu

The effect of CTAB on Na₂SO₄ nucleation in mixed Na₂SO₄/CTAB aerosols by FTIR-ATR technology

The Institute of Chemical Physics, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Shu-Feng Pang,
Received Date: 27 January 2016
Revised Date: 21 February 2016
Accepted Date: 23 February 2016
Available Online: 2 July 2016

Figures(4)

FTIR-ATR technology is used to study the efflorescence kinetic of Na₂SO₄ and mixed Na₂SO₄/CTAB aerosols. As the RH decreased linearly, the ν3-SO₄^-2 band shifts from 1094 cm^-1 to 1132 cm^-1, suggesting the phase transition of Na₂SO₄ from solution to crystal phase (Ⅲ). For pure Na₂SO₄ aerosols, the ERH is 75.1% RH, whereas the efflorescence point ofmixed Na₂SO₄/CTAB aerosols (74.2%) is lower. By further analysis of IR differential spectra, the ratio of Na₂SO₄ crystals in mixed aerosols is only 62.7% and the heterogeneous nucleation rate of Na₂SO₄ in Na₂SO₄/CTAB mixed aerosols is lower than that in pure Na₂SO₄ aerosols. They showed that CTAB assembled into reversed micelle and part Na₂SO₄ droplets are in the core to form core-shell structure, and CTAB shell prevents core Na₂SO₄ solutions from crystallizing. However, the counter ion Br^- for CTAB reversed micelle can interact with Na⁺ ions, which decreases the crystallization rate of free Na₂SO₄ droplets and ERH is delayed.
- FTIR-ATR,
- Na₂SO₄/CTAB,
- Efflorescence,
- Nucleation rate,
- RH
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The effect of CTAB on Na₂SO₄ nucleation in mixed Na₂SO₄/CTAB aerosols by FTIR-ATR technology