Citation: Cui-Cui Zhuang, Jia Feng, Hong Xu, Ling Li, Xiao-Wei Liu. Synthesis of boron nitride nanotube films with a nanoparticle catalyst[J]. Chinese Chemical Letters, ;2016, 27(6): 871-874. doi: 10.1016/j.cclet.2016.01.034 shu

Synthesis of boron nitride nanotube films with a nanoparticle catalyst

MEMS Center, Harbin Institute of Technology, Harbin 150001, China

Received Date: 13 October 2015
Revised Date: 25 November 2015

Fund Project: This work was financially supported by the National Natural Science Funds of China (No. 61404036), the National Basic Research Program of China (No. 2012CB934104), the Fundamental Research Funds for the Central Universities (Nos. HIT.NSRIF. 2015039, 01508536).

Boron nitride nanotube (BNNT) films were synthesized by combining ball milling and thermal chemical vapor deposition (CVD) using nano-Fe₃O₄ as a catalyst. The as-produced BNNTs have a bamboo-like structure and have a diameter in the range of 50~200 nm with an average length of more than 40 mm. Moreover, BNNT nanojunction structures were synthesized. The structure and morphology of the BNNTs were characterized by XRD, SEM, TEM and HRTEM. The possible growth mechanism of BNNTs and BNNT nanojunction structures were proposed. Though the BNNT films were observed, out of our expectation, BNNTs with thin tube wall and small average diameter have not been achieved, and this could be mainly ascribed to the aggregation of the nanoparticle catalyst, resulting in greater catalyst particles during the process of BNNT growth. This result will provide a promising approach to obtain the desired shape of BNNTs and produce branched junctions of BNNTs.
- BNNT films,
- Nano-Fe₃O₄,
- Nanoparticle catalyst,
- Ball milling,
- Microstructure
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