Citation: You-Hua Xiao, Yu Shao, Xu-Xu Ye, Hao Cui, De-Lian Wang, Xia-Heng Zhou, Sheng-Ling Sun, Lin Cheng. Microporous aromatic polyimides derived from triptycene-based dianhydride[J]. Chinese Chemical Letters, ;2016, 27(03): 454-458. doi: 10.1016/j.cclet.2015.12.018 shu

Microporous aromatic polyimides derived from triptycene-based dianhydride

1.
Department of Polymer Science & Materials, Huaqiao University, Xiamen 361021, China

Corresponding author: Lin Cheng,
Received Date: 30 June 2015
Available Online: 22 November 2015
Fund Project: We thank the National Natural Science Foundation of China (No.51473055) for financial support. (No.51473055)

A novel triptycene-based dianhyride as a shape-persistent building block with high internal free volume was conveniently synthesized via solvothermal method. Subsequently, three all-aromatic polyimides, PIa, PIb and PIc, were prepared by a one-step polycondensation of triptycene-2,3,6,7-tetracarboxylic dianhydride with 2,2'-bis(trifluoromethyl)benzidine, m-tolidine and 3,3',5,5'-tetramethylbenzidine, respectively. The corresponding polymers exhibit good solubility, excellent thermal stability, significant microporosity with large BET surface areas of up to 623 m² g^-1, as well as an unexpected optical property with a transmittance of 85% at 450 nm as~20 μm membranes.
- Triptycene,
- Symmetry,
- Dianhydride,
- Polyimide,
- Solvothermal synthesis,
- Microporous polymer
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沈阳化工大学材料科学与工程学院沈阳 110142