Citation: Viran P. Mahida, Manish P. Patel. Superabsorbent amphoteric nanohydrogels:Synthesis, characterization and dyes adsorption studies[J]. Chinese Chemical Letters, ;2016, 27(03): 471-474. doi: 10.1016/j.cclet.2015.12.015 shu

Superabsorbent amphoteric nanohydrogels:Synthesis, characterization and dyes adsorption studies

Viran P. Mahida ,
Manish P. Patel ^,

1.
Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar 388120, Gujarat, India

Corresponding author: Manish P. Patel,
Received Date: 13 May 2015
Available Online: 21 September 2015
Fund Project: This work was provided by University Grants Commission, New Delhi (No.F.39-685/2010(SR)) (No.F.39-685/2010(SR)

The goal of the present research is to remove high percentage of cationic and anionic dyes such as, Neutral Red, Safranin O and Indigo Carmine from aqueous solutions by poly(NIPAAm/N,N-diallylpyrrolidinium bromide/AA) superabsorbent amphoteric nanohydrogels synthesized using the inverse microemulsion polymerization method. Effect of various parameters such as, treatment time, initial dye concentration, pH and adsorbent dose were investigated. Furthermore, kinetics and isotherms adsorption models were applied to determine the maximum adsorption and mechanism for adsorption, which shows that adsorption obeyed the pseudo-second order kinetics. Fromthe results, removal of dyes within the nanohydrogel was found to be in the order:AB-74< BR-2 ≤BR-5.
- Adsorption,
- Dyes,
- Superabsorbent,
- Nanohydrogel
1. [1]
  [1] L.L. Fan, Y. Zhang, X.J. Li, et al., Removal of alizarin red from water environment using magnetic chitosan with Alizarin Red as imprinted molecules, Colloids Surf., B:Biointerfaces 91(2012) 250-257.
2. [2]
  [2] (Ⅰ). Ali, M. Asim, T.A. Khan, Low cost adsorbents for the removal of organic pollutants from wastewater, J. Environ. Manage. 113(2012) 170-183.
3. [3]
  [3] M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. (Ⅰ)dris, Cationic and anionic dye adsorption by agricultural solid wastes:a comprehensive review, Desalination 280(2011) 1-13.
4. [4]
  [4] Y.J. Tang, X. Wang, L.H. Zhu, et al., Removal of methyl orange from aqueous solutions with poly(acrylic acid-co-acrylamide) superabsorbent resin, Polym. Bull. 70(2013) 905-918.
5. [5]
  [5] H. Yao, X.M. You, Q. Lin, et al., Multi-stimuli responsive metal-organic gel of benzimidazol-based ligands with lead nitrate and their use in removal of dyes from waste-water, Chin. Chem. Lett. 24(2013) 703-706.
6. [6]
  [6] S. Gokturk, S. Kaluc, Removal of selected organic compounds in aqueous solutions by activated carbon, J. Environ. Sci. Technol. 1(2008) 111-123.
7. [7]
  [7] J. Zhang, Q.Q. Shi, C.L. Zhang, et al., Adsorption of Neutral Red onto Mn-impregnated activated carbons prepared from Typha orientalis, Bioresour. Technol. 99(2008) 8974-8980.
8. [8]
  [8] E. Karadağ, O.B. Üzüm, A study on water and dye sorption capacities of novel ternary acrylamide/sodium acrylate/PEG semi (Ⅰ)PN hydrogels, Polym. Bull. 68(2012) 1357-1368.
9. [9]
  [9] E. Karadağ, B. Hasgül, S. Kundakci, O.B. Uzum, et al., Montmorillonite loaded highly swollen AAm/AMPS hydrogels and semi-(Ⅰ)PNs with PEG as a novel composite polymeric sorbent for water and dye sorption, Polym.Plast. Technol. Eng. 53(2014) 1259-1271.
10. [10]
  [10] J.J. Wang, F. Liu, Enhanced adsorption of heavy metal ions onto simultaneous interpenetrating polymer network hydrogels synthesized by UV irradiation, Polym. Bull. 70(2013) 1415-1430.
11. [11]
  [11] Y.N. Patel, M.P. Patel, A new fast swelling poly[DAPB-co-DMAAm-co-AASS] superabsorbent hydrogel for removal of anionic dyes from water, Chin. Chem. Lett. 24(2013) 1005-1007.
12. [12]
  [12] F.M.Pavel,Microemulsionpolymerization, J. DispersionSci.Technol.25(2004)1-16.
13. [13]
  [13] N. Sahiner, Hydrogel nanonetworks with functional core-shell structure, Eur. Polym. J. 43(2007) 1709-1717.
14. [14]
  [14] P.V. Dadhaniya, M.P. Patel, R.G. Patel, Removal of anionic dyes from aqueous solution using poly[N-vinyl pyrrolidone/2-(methacryloyloxyethyl) trimethyl ammonium chloride] superswelling hydrogels, Polym. Bull. 58(2007) 359-369.
15. [15]
  [15] M. Kaplan, H. Kasgoz, Hydrogel nanocomposite sorbents for removal of basic dyes, Polym. Bull. 67(2011) 1153-1168.
16. [16]
  [16] P.V. Dadhaniya, M.P. Patel, R.G. Patel, Swelling and dye adsorption study of novel superswelling[Acrylamide/N-vinylpyrrolidone/3(2-hydroxyethyl carbamoyl) acrylic acid] hydrogels, Polym. Bull. 57(2006) 21-31.
17. [17]
  [17] V.P. Mahida, M.P. Patel, Synthesis of new superabsorbent poly(N(Ⅰ)PAAm/AA/Nallylisatin) nanohydrogel for effective removal of As(V) and Cd(Ⅱ) toxic metal ions, Chin. Chem. Lett. 25(2014) 601-604.
18. [18]
  [18] H. Wang, X.Z. Yuan, Z.B. Wu, et al., Removal of basic dye from aqueous solution using Cinnamomum camphora sawdust:kinetics, isotherms, thermodynamics, and mass-transfer processes, Sep. Sci. Technol. 49(2014) 2689-2699.
19. [19]
  [19] S.S. Li, X.Z. Kong, X.B. Jiang, X.L. Zhu, A novel and simple pathway to synthesis of porous polyurea absorbent and its tests on dye adsorption and desorption, Chin. Chem. Lett. 24(2013) 287-290.
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