Citation: Wei Su, Rong Li, Yan-Jun Xing. Preparation and characterization of hollow carambola-shaped silver sulfide microspheres using a microwave-assisted template-free method[J]. Chinese Chemical Letters, ;2016, 27(03): 451-453. doi: 10.1016/j.cclet.2015.12.009 shu

Preparation and characterization of hollow carambola-shaped silver sulfide microspheres using a microwave-assisted template-free method

Wei Su ^a ,
Rong Li ^b ,
Yan-Jun Xing ^a,,

a.
a. College of Chemistry, Chemical Engineering and Biotechnology of Donghua University, Shanghai 201620, China;
b.
b. National Engineering Research Center for Dyeing & Finishing of Textiles, Shanghai 201620, China

Corresponding author: Yan-Jun Xing,
Received Date: 11 September 2015
Available Online: 5 November 2015
Fund Project: This work was supported by the Fundamental Research Funds for the Central Universities (No.2232013A3-05) (No.2232013A3-05)

A simple and convenient method, free of template, has been proposed to synthesize hollow carambolashaped Ag₂S microspheres with AgNO₃, thiourea (TU), NaCl and diethanolamine as reagents using a microwave-assisted method, at low temperatures of below 100℃. Powder X-ray diffraction (XRD), scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM) were employed to characterize the morphology and composition of those microspheres. The results indicated that the hollow carambola-shaped silver sulfide microspheres (with high purity and homogeneous morphology) were prepared by an Ostwald ripening process. A possible formation mechanism of hollow carambola-shaped Ag₂S microspheres was proposed.
- Silver sulfide,
- Hollow carambola-shaped,
- Microwave-assisted method,
- Template-free
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