Citation: Yong-Tao Gao, Lin-Man Zhao, Fu-Qing Pang, Xiu-Juan Qi, Jing-Lun Huang, Fu-Xue Chen. Synthesis and properties of energetic salts based on 3-nitro-5-nitroimino-1,2,4-oxadiazole[J]. Chinese Chemical Letters, ;2016, 27(03): 433-436. doi: 10.1016/j.cclet.2015.12.008 shu

Synthesis and properties of energetic salts based on 3-nitro-5-nitroimino-1,2,4-oxadiazole

a.
a. School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China;
b.
b. Research Center of Energetic Material Genome Science, Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621050, China

Corresponding author: Fu-Xue Chen,
Received Date: 23 September 2015
Available Online: 20 November 2015
Fund Project:

A series of 3-nitro-5-nitroimino-1,2,4-oxadiazole-based energetic salts were synthesized from 3-nitro-5-nitroimino-1,2,4-oxadiazole anion and nitrogen-rich cations. They were fully characterized by IR, elemental analysis and NMR spectroscopy. The structure of triaminoguanidinium salt (1-e) was confirmed by single crystal X-ray diffraction. All salts showed good thermal stability with decomposed temperature ranging from 155℃ to 258℃, and positive heats of formation from 226.0 kJ/mol to 554.1 kJ/mol. Thus, the theoretic detonation pressure was predicted from 28.70 GPa to 37.60 GPa and velocities from 8526 m/s to 9354 m/s. Among them, guanidinium salt (1-c) exhibited both high decomposition temperature (258℃) and detonation velocity (9319 m/s).
- Energetic salts,
- Explosives,
- Ionic salts,
- Nitrogen-rich cations,
- Nitroamines,
- 1,2,4-Oxadiazole
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