Citation: Xiao-Wei Cui, Shi-Yan Chen, Chuan-Zeng Wang, Wen-Xuan Zhao, Tao Sun, Xin-Long Ni, Yun-Qian Zhang, Zhu Tao. Involvement of unusual noncovalent interactions in the self-assembly of cucurbit[6]uril with[CdCl₄]^2- anions[J]. Chinese Chemical Letters, ;2016, 27(01): 173-177. doi: 10.1016/j.cclet.2015.10.007 shu

Involvement of unusual noncovalent interactions in the self-assembly of cucurbit[6]uril with[CdCl₄]^2- anions

1.
a Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;
2.
b Key Laboratory of Guizhou High Performance Computational Chemistry, Guizhou University, Guiyang 550025, China

Corresponding author: Xin-Long Ni, Yun-Qian Zhang,
Received Date: 11 August 2015
Available Online: 10 September 2015
Fund Project: This work was supported by the National Natural Science Foundation of China(No. 21361006) (No. 21361006) "Chun-Hui" Fund of Chinese Ministry of Education(No. Z2011037) (No. Z2011037)Guizhou University(No. 20127027). (No. 20127027)

The[CdCl₄]^2- anion as a structure inducer has proved to be useful in the construction of cucurbit[n]urilmetal coordination architectures and materials. In order to better understand the role and influence of the structure inducer in Q[n] systems, we report herein the self-assembly of Q[6] solely in the presence of[CdCl₄]^2- anions and in the presence of both a linear cationic organic guest and[CdCl₄]^2- anions. X-ray diffraction analysis revealed that 1D Q[6] porous channels were formed by the noncovalent interactions between Q[6] and[CdCl₄]^2- anions, but the "honeycomb effect" was not observed in the present study. However, it seems that the "honeycomb effect" and the self-assembly of Q[6] with[CdCl₄]^2- anions can be significantly modified and switched in the presence of a linear cationic dibutylamine guest through some unusual noncovalent interactions.
- Cucurbit[6]uril,
- [CdCl₄]^2- anions,
- Cationic guest,
- Honeycomb effect,
- Assembly
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Involvement of unusual noncovalent interactions in the self-assembly of cucurbit[6]uril with[CdCl4]2- anions

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通讯作者: 陈斌, bchen63@163.com

Involvement of unusual noncovalent interactions in the self-assembly of cucurbit[6]uril with[CdCl₄]^2- anions