Citation: Wei Zhang, Zhi-Gang Xie. Fabrication of palladium nanoparticles as effective catalysts by using supramolecular gels[J]. Chinese Chemical Letters, ;2016, 27(01): 77-80. doi: 10.1016/j.cclet.2015.09.009 shu

Fabrication of palladium nanoparticles as effective catalysts by using supramolecular gels

Wei Zhang ^a,b ,
Zhi-Gang Xie ^a,,

1.
a State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhi-Gang Xie,
Received Date: 15 July 2015
Available Online: 22 August 2015
Fund Project: This work was supported by the National Natural Science Foundation of China(No. 91227118). (No. 91227118)

Two-component supramolecular gels were made through self-assembly of tetrazolyl derivatives and Pd(OAc)₂. The robust gels indicated high storage modulus(>10,000 Pa) and loss modulus, which were studied by rheological measurements. The formed Pd nanoparticles(~9 nm) obtained during the formation of the gel showed effective catalytic hydrogenation of nitrobenzene and could be recovered and reused without loss of activity.
- Pd nanoparticles,
- Self-assembly,
- Supramolecular gels,
- Catalysts
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