Citation: Wei Xu, Cai-Feng Ding, Xin-Wen Wang, Xiao-Li Liu, Zhi-Dong Qiu. Two new triterpenoid saponins from notoginseng medicinal fungal substance[J]. Chinese Chemical Letters, ;2015, 26(10): 1298-1302. doi: 10.1016/j.cclet.2015.07.014 shu

Two new triterpenoid saponins from notoginseng medicinal fungal substance

1.
College of Pharmacy, Changchun University of Chinese Medicine, Changchun 130117, China

Corresponding author: Zhi-Dong Qiu,
Received Date: 14 April 2015
Available Online: 25 June 2015
Fund Project:

Two new triterpenoid saponins, named ginsenoside Rh₁₀ (1) and notoginsenoside ST-6 (2), were isolated from notoginseng medicinal fungal substance. Their structures were elucidated by a combination of 1D and 2D NMR, MS and chemical analysis.
- Notoginseng,
- Triterpenoid ginsenoside,
- Ginsenoside Rh₁₀,
- Notoginsenoside ST-6
1. [1]
  [1] B. Chen, H.L. Xu, X.B. Jia, Research progress and thought on processing of Panax notoginseng, Chin. Tradit. Herb. Drugs 44(2013) 482-487.
2. [2]
  [2] X.H. Wang, Q.D. Li, Q.E. Cao, New field for study of TCM through fermentation by microbe, Chin. Tradit. Herb. Drugs 32(2001) 267-268.
3. [3]
  [3] M. Górecki, A. Kamińska, P. Ruśkowska, A. Suszczyńska, J. Frelek, Dimolybdenum method for determination of the absolute configuration of vic-diols-foundations and developments, Pol. J. Chem. 80(2006) 523-534.
4. [4]
  [4] J. Frelek, A. Klimek, P. Ruskowska, Dinuclear transition metal complexes as auxiliary chromophores in chiroptical studies on bioactive compounds, Curr. Org. Chem. 7(2003) 1081-1104.
5. [5]
  [5] M. Górecki, E. Jabłońska, A. Kruszewska, et al., Practical method for the absolute configuration assignment of tert/tert 1,2-diols using their complexes with Mo₂(OAc)₄, J. Org. Chem. 72(2007) 2906-2916.
6. [6]
  [6] L. Di Bari, G. Pescitelli, C. Pratelli, D. Pini, P. Salvadori, Determination of absolute configuration of acyclic 1, 2-diols with Mo₂(OAc)₄. 1. Snatzke's method revisited, J. Org. Chem. 66(2001) 4819-4825.
7. [7]
  [7] M. Politi, N. De Tommasi, G. Pescitelli, et al., Structure and absolute configuration of new diterpenes from Lavandula multifida, J. Nat. Prod. 65(2002) 1742-1745.
8. [8]
  [8] J. Liu, Y.B. Liu, Y.K. Si, et al., New vernocuminosides from the stem barks of Vernonia cumingiana Benth, Steroids 74(2009) 51-61.
9. [9]
  [9] L.F. Han, K.J. Sakah, L.L. Liu, et al., Saponins from roots of Panax notoginseng, Chin. Herb. Med. 6(2014) 159-163.
10. [10]
  [10] B.H. Han, M.H. Park, Y.N. Han, et al., Degradation of ginseng saponins under mild acidic conditions, Planta Med. 44(1982) 146-149.
11. [11]
  [11] W. Xu, J.M. Wu, Z. Zhu, et al., Pentacyclic triterpenoid saponins from Silene viscidula, Helv. Chim. Acta 93(2010) 2007-2014.
12. [12]
  [12] P.Y. Liao, D. Wang, Y.J. Zhang, C.R. Yang, Dammarane-type glycosides from steamed notoginseng, J. Agric. Food Chem. 56(2008) 1751-1756.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142