Citation: Xin-Dong Jiang, Hai-Feng Yu, Jiu-Li Zhao, Chang-Liang Sun, Ying Xie, Lin-Jiu Xiao. A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg²⁺ detection[J]. Chinese Chemical Letters, ;2015, 26(10): 1241-1245. doi: 10.1016/j.cclet.2015.07.002 shu

A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg²⁺ detection

1.
1 College of Applied Chemistry, Key Laboratory of Rare-Earth Chemistry and Applying Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China;
2.
2 Center of Physical and Chemistry Test, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Xin-Dong Jiang, Chang-Liang Sun,
Received Date: 6 May 2015
Available Online: 16 June 2015
Fund Project: This work was supported by the Public Research Foundation of Liaoning Province for the Cause of Science (No. 2014003009) (No. 2014003009) the Foundation of the Education Department of Henan Province for Science and Technology Research Projects (No. 13A150046) (No. 2013304007)

The phosphorus-containing PODIPY 1 as a chemosensor can detect Hg²⁺ by a color change from pink to violet red without the use of any instrumentation. PODIPY 1 was selective to Hg²⁺ with a remarkable absorption change, and addition of other relevant metal ions caused almost no absorption change. The new PODIPY dye 1 was sensitive to various concentrations of Hg²⁺. The energy gap between the HOMO and LUMO of the metal complex 1-Hg²⁺ is smaller than that of chemosensor 1, which is in good agreement with the red shift in the absorption observed upon treatment of 1 with Hg²⁺. The 1-based test strips were easily fabricated and low-cost, useful in practical and efficient Hg²⁺ test kits.
- PODIPY,
- Hg²⁺,
- Colorimetric,
- DFT,
- Chemosensor
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg2+ detection

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通讯作者: 陈斌, bchen63@163.com

A colorimetric chemosensor based on new water-soluble PODIPY dye for Hg²⁺ detection