Citation: Yang Xu, Liang-Sheng Qiang, Yu-Lin Yang, Li-Guo Wei, Ping Wang, Rui-Qing Fan. Enhanced performance of ruthenium dye-sensitized solar cell by employing an organic co-adsorbent of N,N'-bis((pyridin-2-yl)(methyl) methylene)-o-phenylenediamine[J]. Chinese Chemical Letters, ;2016, 27(01): 127-134. doi: 10.1016/j.cclet.2015.06.010 shu

Enhanced performance of ruthenium dye-sensitized solar cell by employing an organic co-adsorbent of N,N'-bis((pyridin-2-yl)(methyl) methylene)-o-phenylenediamine

Yang Xu ^a ,
Liang-Sheng Qiang ^a ,
Yu-Lin Yang ^a,, ,
Li-Guo Wei ^a,b ,
Ping Wang ^a ,
Rui-Qing Fan ^a,,

1.
a Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China;
2.
b College of Environmental and Chemical Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China

Corresponding author: Yu-Lin Yang, Rui-Qing Fan,
Received Date: 14 April 2015
Available Online: 31 May 2015
Fund Project: and the Fundamental Research Funds for the Central Universities(No. HIT. IBRSEM. A201409) (973 Program, No. 2013CB632900)

A pyridine-anchor co-adsorbent of N,N'-bis((pyridin-2-yl)(methyl) methylene)-o-phenylenediamine(named BPPI) is prepared and employed as co-adsorbent in dye-sensitized solar cells(DSSCs). The prepared co-adsorbent could overcome the deficiency of N719 absorption in the low wavelength region of visible spectrum, offset competitive visible light absorption of I₃^-, enhance the spectral responses of the co-adsorbed TiO₂ film in region from 300 nm to 750 nm, suppress charge recombination, prolong electron lifetime, and decrease the total resistance of DSSCs. The optimized cell device co-sensitized by BPPI/N719 dye gives a short circuit current density of 12.98 mA cm^-2, an open circuit voltage of 0.73 V, and a fill factor of 0.66 corresponding to an overall conversion efficiency of 6.22% under standard global AM 1.5 solar irradiation, which is much higher than that of device solely sensitized by N719(5.29%) under the same conditions. Mechanistic investigations are carried out by various spectral and electrochemical characterizations.
- Dye-sensitized solar cells,
- Co-adsorbent,
- Enhanced performance,
- Co-sensitization
1. [1]
  [1] A. Hagfeldt, G. Boschloo, L.C. Sun, L. Koo, H. Pettersso, Dye-sensitized solar cells, Chem. Rev. 110(2010) 6595-6663.
2. [2]
  [2] B. O'Regan, M. Grätzel, A low-cost, high-efficiency solar cell based on dye sensitized colloidal TiO₂ films, Nature 353(1991) 737-740.
3. [3]
  [3] P.J. Cameron, L.M. Peter, Characterization of titanium dioxide blocking layers in dye-sensitized nanocrystalline solar cells, J. Phys. Chem. B 107(2003) 14394-14400.
4. [4]
  [4] M.K. Nazeeruddin, F. de Angelis, S. Fantacci, et al., Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers, J. Am. Chem. Soc. 127(2005) 16835-16847.
5. [5]
  [5] K.M. Guo, M.Y. Li, X.L. Fang, et al., Performance enhancement in dye-sensitized solar cells by utilization of a bifunctional layer consisting of core-shell b-NaYF₄:Er³⁺/Yb³⁺@SiO₂ submicron hexagonal prisms, J. Power Sources 249(2014) 72-78.
6. [6]
  [6] Y.R. Gao, L.L. Chu, W. Guo, T.L. Ma, Snythesis and photoelectric properties of an organic dye containing benzo[1, 2-b:4,5-b'] dithiophene for dye-sensitized solar cells, Chin. Chem. Lett. 24(2013) 149-152.
7. [7]
  [7] Q.P. Liu, Analysis on dye-sensitized solar cells based on Fe-doped TiO₂ by intensity-modulated photocurrent spectroscopy and Mott-Schottky, Chin. Chem. Lett. 25(2014) 953-956.
8. [8]
  [8] Y.Q. Wang, X.L. Gao, B. Song, Y.L. Gu, Y.M. Sun, Photoelectrochemical properties of MWCNT-TiO₂ hybrid materials as a counter electrode for dye-sensitized solar cells, Chin. Chem. Lett. 25(2014) 491-495.
9. [9]
  [9] A. Yella, H.W. Lee, H.N. Tsao, et al., Porphyrin-sensitized solar cells with cobalt(Ⅱ/ⅡI)-based redox electrolyte exceed 12 percent efficiency, Science 334(2011) 629-634.
10. [10]
  [10] S.P. Singh, M. Chandrasekharam, K.S.V. Gupta, et al., Co-sensitization of amphiphilic ruthenium(Ⅱ) sensitizer with a metal free organic dye:improved photovoltaic performance of dye sensitized solar cells, Org. Electron. 14(2013) 1237-1241.
11. [11]
  [11] G.D. Sharma, M.S. Roy, S.P. Singh, Improvement in the power conversion efficiency of thiocyanate-free Ru(Ⅱ) based dye sensitized solar cells by cosensitization with a metal-free dye, J. Mater. Chem. 22(2012) 18788-18792.
12. [12]
  [12] L.Y. Han, A. Islam, H. Chen, et al., High-efficiency dye-sensitized solar cell with a novel co-adsorbent, Energy Environ. Sci. 5(2012) 6057-6060.
13. [13]
  [13] H. Ozawa, R. Shimizu, H. Arakawa, Significant improvement in the conversion efficiency of black-dye-based dye-sensitized solar cells by cosensitization with organic dye, RSC Adv. 2(2012) 3198-3200.
14. [14]
  [14] M. Mojiri-Foroushani, H. Dehghani, N. Salehi-Vanani, Enhancement of dye-sensitized solar cells performances by improving electron density in conduction band of nanostructure TiO₂ electrode with using a metalloporphyrin as additional dye, Electrochim. Acta 92(2013) 315-322.
15. [15]
  [15] P.J. Holliman, M. Mohsen, A. Connell, et al., Ultra-fast co-sensitization and trisensitization of dye-sensitized solar cells with N719, SQ1 and triarylamine dyes, J. Mater. Chem. 22(2012) 13318-13327.
16. [16]
  [16] K.M. Lee, Y.C. Hsu, M. Ikegami, et al., Co-sensitization promoted light harvesting for plastic dye-sensitized solar cells, J. Power Sources 196(2011) 2416-2421.
17. [17]
  [17] S.Q. Fan, C. Kim, B. Fang, et al., Dye heterogeneously positioning on a single TiO₂ electrode, J. Phys. Chem. C 115(2011) 7747-7754.
18. [18]
  [18] G.D. Sharma, D. Daphnomili, K.S.V. Gupta, et al., Enhancement of power conversion efficiency of dye-sensitized solar cells by co-sensitization of zinc-porphyrin and thiocyanate-free ruthenium(Ⅱ) terpyridine dyes and graphene modified TiO₂ photoanode, RSC Adv. 3(2013) 22412-22420.
19. [19]
  [19] Z.S. Wu, Y.N. Wei, Z.W. An, X.B. Chen, P. Chen, Co-sensitization of N719 with an organic dye for dye-sensitized solar cells application, Bull. Korean Chem. Soc. 35(2014) 1449-1454.
20. [20]
  [20] S. Chang, H.D. Wang, L.T.L. Lee, et al., Panchromatic light harvesting by N719 with a porphyrin molecule for high-performance dye-sensitized soalr cells, J. Mater. Chem. C 2(2014) 3521-3526.
21. [21]
  [21] Y. Harima, T. Fujita, Y. Kano, et al., Lewis-acid sites of TiO₂ surface for adsorption of organic dye having pyridyl group as anchoring unit, J. Phys. Chem. C 117(2013) 16364-16370.
22. [22]
  [22] Y. Ooyama, S. Inoue, T. Nagano, et al., Dye-sensitized solar cells based on donoracceptor p-conjugated fluorescent dyes with a pyridine ring as an electronwithdrawing anchoring group, Angew. Chem. Int. Ed. 50(2011) 7429-7433.
23. [23]
  [23] D.B. Kunag, S. Ito, B. Wenger, et al., High molar extinction coefficient heteroleptic ruthenium complexes for thin film dye-sensitized solar cells, J. Am. Chem. Soc. 128(2006) 4146-4154.
24. [24]
  [24] G.D. Sharma, S.P. Singh, R. Kurchania, R.J. Ball, Cosensitization of dye sensitized solar cells with a thiocyanate free Ru dye and a metal free dye containing thienylfluorene conjugation, RSC Adv. 3(2013) 6036-6043.
25. [25]
  [25] C.Y. Lin, C.F. Lo, L.Y. Luo, et al., Design and characterization of novel porphyrins with oligo(phenylethylnyl) links of varied length for dye-sensitized solar cells:synthesis and optical, electrochemical, and photovoltaic investigation, J. Phys. Chem. C 113(2009) 755-764.
26. [26]
  [26] C.M. Cardona, W. Li, A.E. Kaifer, D. Stockdale, G.C. Bazan, Electrochemical considerations for determining absolute frontier orbital energy levels of conjugated polymers for solar cell applications, Adv. Mater. 23(2011) 2367-2371.
27. [27]
  [27] G. Boschloo, L. Häggman, A. Hagfeldt, Quantification of the effect of 4-tertbutylpyridine addition to I^-/I₃^- redox electrolytes in dye-sensitized nanostructured TiO₂ solar cells, J. Phys. Chem. B 110(2006) 13144-13150.
28. [28]
  [28] K.R.J. Thomas, Y.C. Hsu, J.T. Lin, et al., 2,3-disubstituted thiophene-based organic dyes for solar cells, Chem. Mater. 20(2008) 1830-1840.
29. [29]
  [29] H. Irie, Y. Watanabe, K. Hashimoto, Nitrogen-concentration dependence on photocatalytic activity of TiO_2-xN_x powders, J. Phys. Chem. B 107(2003) 5483-5486.
30. [30]
  [30] L.Q. Jing, X.J. Sun, J. Shang, et al., Review of surface photovoltage spectra of nanosized semiconductor and its applications in heterogeneous photocatalysis, Sol. Energy Mater. Sol. Cells 79(2003) 133-151.
31. [31]
  [31] G.D. Sharma, G.E. Zervaki, P.A. Angaridis, et al., Stepwise co-sensitization as a useful tool for enhancement of power conversion efficiency of dye-sensitized solar cells:the case of an unsymmetrical porphyrin dyad and a metal-free organic dye, Org. Electron. 15(2014) 1324-1337.
32. [32]
  [32] X. Jiang, T. Marinado, E. Gabrielsson, et al., Structural modification of organic dyes for efficient coadsorbent-free dye-sensitized solar cells, J. Phys. Chem. C 114(2010) 2799-2805.
33. [33]
  [33] P. Salvatori, G. Marotta, A. Cinti, et al., Supramolecular interactions of chenodeoxycholic acid increase the efficiency of dye-sensitized solar cells based on a cobalt electrolyte, J. Phys. Chem. C 117(2013) 3874-3887.
34. [34]
  [34] G.D. Sharma, S.P. Singh, P. Nagarjuna, et al., Efficient dye-sensitized solar cells based on cosensitized metal free organic dyes with complementary absorption spectra, J. Renew. Sustain. Energy 5(2013) 043107.
35. [35]
  [35] K. Mukherjee, T.H. Teng, R. Jose, S. Ramakrishna, Electron transport in electrospun TiO₂ nanofiber dye-sensitized solar cells, Appl. Phys. Lett. 95(2009) 012101.
36. [36]
  [36] J. Bisquert, Theory of the impedance of electron diffusion and recombination in a thin layer, J. Phys. Chem. B 106(2002) 325-333.
37. [37]
  [37] J. Bisquert, Chemical capacitance of nanostructured semiconductors:its origin and significance for nanocomposite solar cells, Phys. Chem. Chem. Phys. 5(2003) 5360-5364.
38. [38]
  [38] A. Zaban, A. Meier, B.A. Gregg, Electric potential distribution and short-range screening in nanoporous TiO₂ electrodes, J. Phys. Chem. B 101(1997) 7985-7990.
39. [39]
  [39] S. Ito, P. Liska, P. Comte, et al., Control of dark current in photoelectrochemical(TiO₂/I^-/I₃^-) and dye-sensitized solar cells, Chem. Commun. 34(2005) 4351-4353.
40. [40]
  [40] J. Bisquert, A. Zaban, M. Greenshtein, I. Mora-Seró, Determination of rate constants for charge transfer and the distribution of semiconductor and electrolyte electronic energy levels in dye-sensitized solar cells by open-circuit photovoltage decay method, J. Am. Chem. Soc. 126(2004) 13550-13559.
41. [41]
  [41] K. Fan, W. Zhang, T.Y. Peng, J.N. Chen, F. Yang, Application of TiO₂ fusiform nanorods for dye-sensitized solar cells with significantly improved efficiency, J. Phys. Chem. C 115(2011) 17213-17219.
42. [42]
  [42] H. Yua, S.Q. Zhang, H.J. Zhao, G. Will, P. Liu, An efficient and low-cost TiO₂ compact layer for performance improvement of dye-sensitized solar cells, Electrochim. Acta 54(2009) 1319-1324.
43. [43]
  [43] A. Zaban, M. Greenshtein, J. Bisquert, Determination of the electron lifetime in nanocrystalline dye solar cells by open-circuit voltage decay measurements, ChemPhysChem 4(2003) 859-864.
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