Citation: Koon-Kee Kow, Kamaliah Sirat. Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis[J]. Chinese Chemical Letters, ;2015, 26(10): 1311-1314. doi: 10.1016/j.cclet.2015.05.049 shu

Novel manganese(II)-based deep eutectic solvents: Synthesis and physical properties analysis

Koon-Kee Kow ^, ,
Kamaliah Sirat

1.
Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, Malaysia

Corresponding author: Koon-Kee Kow,
Received Date: 26 February 2015
Available Online: 19 May 2015

Type IV deep eutectic solvent (DES) involves the formation of metal-based eutectics from metal salts or metal salt hydrate incombination with various hydrogen-bonddonors(HBDs) suchas urea, ethylene glycol or acetamide. In current study, twodistinguished approaches were used to synthesize potential DESs, given as the direct heating and the evaporatingmethods. Successful synthesized DESswere subjected forphysical properties characterization by Fourier TransformInfrared (FTIR) Spectroscopy, thermal stability, viscosity, and conductivity analyses. Five novelmanganese (II)-basedDESswere successfully synthesized as reported in this study. Data obtained indicated that the MnCl₂·4H₂O·acetamide DES exhibits the lowest freezing point (27.5℃), highest thermal stability (193℃ point of dehydration), lowest viscosity (η=112.8 cP) and the highest conductivity (0.12723 mS/cm). The findings obtained reveal the characteristics, nature or features of synthesized DESs as potential industrial solvents.
- Ionic liquid,
- Deep eutectic solvents,
- Manganese,
- Solvent synthesis,
- Physical properties
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沈阳化工大学材料科学与工程学院沈阳 110142