Citation: Wei-Yi Zhang, Guo-Song Chen. A facile approach to prepare hybrid nanoparticles with morphology controlled by the thickness of glyco-shell[J]. Chinese Chemical Letters, ;2015, 26(7): 847-850. doi: 10.1016/j.cclet.2015.05.022 shu

A facile approach to prepare hybrid nanoparticles with morphology controlled by the thickness of glyco-shell

Wei-Yi Zhang ,
Guo-Song Chen ^,

1.
The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai 200433, China

Corresponding author: Guo-Song Chen,
Received Date: 1 April 2015
Available Online: 28 April 2015
Fund Project: National Natural Science Foundation of China (No. 91227203, 21474020 and 51322306) (No. 2011CB932503332)

Herein, we designed a novel amphiphilic triblock glycopolymer poly(oligo(ethyleneglycol) methacrylate)- block-poly(maltopyranoside methacrylate)-block-polystyrene (POMA-b-PMal-b-PS) via the combination of reversuble addition-fragmentation chain transfer (RAFT) polymerization and postpolymerization modification. The micelles with core-shell-corona structures were prepared by direct self-assembly of this glycopolymer in water. We found that these micelles can be used in in situ formation and stabilization of AuNPs. By controlling the thickness of glyco-shell, we successfully obtained Janus particles and raspberry-like particles with AuNPs in the sugar shell.
- Glycopolymer,
- Self-assembly,
- Gold nanoparticles,
- Morphology
1. [1]
  [1] A. Ghadban, L. Albertin, Synthesis of glycopolymer architectures by reversibledeactivation radical polymerization, Polymers 5 (2013) 431–526.
2. [2]
  [2] C. Zheng, Q.Q. Guo, Z.M. Wu, et al., Amphiphilic glycopolymer nanoparticles as vehicles for nasal delivery of peptides and proteins, Eur. J. Pharm. Sci. 49 (2013) 474–482.
3. [3]
  [3] A.L. Parry, N.A. Clemson, J. Ellis, et al., ‘Multicopy Multivalent' glycopolymerstabilized gold nanoparticles as potential synthetic cancer vaccines, J. Am. Chem. Soc. 135 (2013) 9362–9365.
4. [4]
  [4] T. Xing, X.Z. Yang, L.Y. Fu, L.F. Yan, Near infrared fluorescence probe and galactose conjugated amphiphilic copolymer for bioimaging of HepG2 cells and endocytosis, Polym. Chem. 4 (2013) 4442–4449.
5. [5]
  [5] M.H. Mashhadizadeh, R.P. Talemi, Application of diazo-thiourea and gold nanoparticles in the design of a highly sensitive and selective DNA biosensor, Chin. Chem. Lett. 26 (2015) 160–166.
6. [6]
  [6] X.H. Lv, L.P. Wang, G. Li, et al., Preparation and characterization of optically functional hollow sphere hybrid materials by surface-initiated RATRP and “click” chemistry, Chin. Chem. Lett. 24 (2013) 335–337.
7. [7]
  [7] M. Takara, M. Toyoshima, H. Seto, Y. Hoshino, Y. Miura, Polymer-modified gold nanoparticles via RAFT polymerization: a detailed study for a biosensing application, Polym. Chem. 5 (2014) 931–939.
8. [8]
  [8] A. Pfaff, A. Schallon, T.M. Ruhland, et al., Magnetic and fluorescent glycopolymer hybrid nanoparticles for intranuclear optical imaging, Biomacromolecules 12 (2011) 3805–3811.
9. [9]
  [9] K. Kuroda, T. Ishida, M. Haruta, Reduction of 4-nitrophenol to 4-aminophenol over Au nanoparticles deposited on PMMA, J. Mol. Catal. A: Chem. 298 (2009) 7–11.
10. [10]
  [10] K. Esumi, T. Hosoya, A. Suzuki, K. Torigoe, Spontaneous formation of gold nanoparticles in aqueous solution of sugar-persubstituted poly(amidoamine) dendrimers, Langmuir 16 (2000) 2978–2980.
11. [11]
  [11] L. Su, C.M. Wang, F. Polzer, et al., Glyco-inside micelles and vesicles directed by protection–deprotection chemistry, ACS Macro Lett. 3 (2014) 534–539.
12. [12]
  [12] Y.X. Zhang, X.D. Hao, Z.P. Diao, Templated self-assembly of Au–TiO₂ binary nanoparticles–nanotubes, Chin. Chem. Lett. 25 (2014) 874–878.
13. [13]
  [13] T. Chen, M.X. Yang, X.J. Wang, L.H. Tan, H.Y. Chen, Controlled assembly of eccentrically encapsulated gold nanoparticles, J. Am. Chem. Soc. 130 (2008) 11858–11859.
14. [14]
  [14] J. He, M.T. Perez, P. Zhang, et al., A general approach to synthesize asymmetric hybrid nanoparticles by interfacial reactions, J. Am. Chem. Soc. 134 (2012) 3639– 3642.
15. [15]
  [15] W.P. Li, V. Shanmugam, C.C. Huang, et al., Eccentric inorganic-polymeric nanoparticles formation by thermal induced cross-linked esterification and conversion of eccentricity to raspberry-like Janus, Chem. Commun. 49 (2013) 1609–1611.
16. [16]
  [16] N. Ali, S.Y. Park, Micellar structures of poly(styrene-b-4-vinylpyridine)s in THF/ Toluene mixtures and their functionalization with gold, Langmuir 24 (2008) 9279–9285.
17. [17]
  [17] T. Premkumar, K. Lee, K.E. Geckeler, Shape-tailoring of gold nanostructures: can a detergent act as the reducing or protecting agent? Nanoscale 3 (2011) 1482– 1484.
18. [18]
  [18] R. Fenger, E. Fertitta, H. Kirmse, A.F. Thü nemann, K. Rademann, Size dependent catalysis with CTAB-stabilized gold nanoparticles, Phys. Chem. Chem. Phys. 14 (2012) 9343–9349.
19. [19]
  [19] Y.Wang, G.W.Wei, W.Q. Zhang, et al., Responsive catalysis of thermoresponsive micelle-supported gold nanoparticles, J. Mol. Catal. A: Chem. 266 (2007) 233–238.
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沈阳化工大学材料科学与工程学院沈阳 110142