Citation: Peng-Zhong Chen, Hai-Rong Zheng, Li-Ya Niu, Yu-Zhe Chen, Li-Zhu Wu, Chen-Ho Tung, Qing-Zheng Yang. A BODIPY analogue from the tautomerization of sodium 3-oxide BODIPY[J]. Chinese Chemical Letters, ;2015, 26(6): 631-635. doi: 10.1016/j.cclet.2015.04.018 shu

A BODIPY analogue from the tautomerization of sodium 3-oxide BODIPY

1.
a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
2.
b University of the Chinese Academy of Sciences, Beijing 100049, China;
3.
c College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: Qing-Zheng Yang,
Received Date: 13 March 2015
Available Online: 2 April 2015
Fund Project: This work was financially supported by the 973 program (Nos. 2013CB933800, 2013CB834505) (Nos. 2013CB933800, 2013CB834505) National Natural Science Foundation of China (Nos. 21222210, 21102155, 91027041) (Nos. 21222210, 21102155, 91027041)

The introduction of hydroxy group to the 3-or 5-position of 4,4-difluoro-4-bora-3a,4a-diazaindacene (BODIPY) results in unexpected tautomerization to BDPONa with interesting structural and photophysical properties. The core of BDPONa is an anion with sodium cation as counter-ion. BDPONa displays strong fluorescence in organic solvents.
- Bodipy,
- Substitution reaction,
- Tautomerization,
- Sodium salt
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