Citation: Yue-Jiao Li, Chuan-Xiong Zhou, Shi Chen, Feng Wua, Liang Hong. Nd³⁺-doped Li₃V₂(PO₄)₃ cathode material with high rate capability for Li-ion batteries[J]. Chinese Chemical Letters, ;2015, 26(8): 1004-1007. doi: 10.1016/j.cclet.2015.03.013 shu

Nd³⁺-doped Li₃V₂(PO₄)₃ cathode material with high rate capability for Li-ion batteries

Yue-Jiao Li ^a,b,, ,
Chuan-Xiong Zhou ^a ,
Shi Chen ^a,b ,
Feng Wua ^a,b ,
Liang Hong ^a

1.
a Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, China;
2.
b National Development Center for High Technology Green Material, Beijing 100081, China

Corresponding author: Yue-Jiao Li,
Received Date: 16 January 2015
Available Online: 27 February 2015
Fund Project: This work was supported by the National Key Program for Basic Research of China (No. 2009CB220100) (No. 2009CB220100) National High-tech 863 Key Program (No. 2011AA11A235) (No. 2011AA11A235)

A series of Nd³⁺-doped Li₃Nd_xV_2-x(PO₄)₃ (x = 0.00, 0.02, 0.05, 0.08 or 0.1) composites are synthesized by the rheological phase reaction method. The XRD results indicate that Nd³⁺ ions have been successfully merged into a lattice structure. Doped samples show good electrochemical performance in high discharge rate and long cycle. In the potential range of 3.0-4.3 V, Li₃Nd_0.08V_1.92(PO₄)₃ exhibits an initial discharge capacity of 115.8 mAh/g at 0.2 C and retain 80.86% of capacity retention at 2 C in the 51st cycle. In addition, Li₃Nd_0.05V_1.95(PO₄)₃ holds at 100.4 mAh/g after 80 cycles at 0.2 C with a capacity retention of 92.4%. Finally, the CV test proves that the potential polarization of Li₃Nd_0.08V_1.92(PO₄)₃ decreased compared with the un-doped one.
- Li₃V₂(PO₄)₃,
- Rheological phase reaction,
- Nd³⁺ dope,
- Electrochemical performance
1. [1]
  [1] K. Kesavan, C.M. Mathew, S. Rajendran, Lithium ion conduction and ion-polymer interaction in poly(vinyl pyrrolidone) based electrolytes blended with different plasticizers, Chin. Chem. Lett. 25 (2014) 1428-1434.
2. [2]
  [2] X. Wang, Y.J. Yang, Y. Ma, J.N. Yao, Controlled synthesis of multi-shelled transition metal oxide hollow structures through one-pot solution route, Chin. Chem. Lett. 24 (2013) 1-6.
3. [3]
  [3] C. Delacourt, L. Laffont, R. Bouchet, et al., Toward understanding of electrical limitations (electronic, ionic) in LiMPO₄ (M = Fe, Mn) electrode materials, J. Electrochem. Soc. 152 (2005) A913-A921.
4. [4]
  [4] S.F. Yang, P.Y. Zavalij, M.S. Whittingham, Hydrothermal synthesis of lithium iron phosphate cathodes, Electrochem. Commun. 3 (2001) 505-508.
5. [5]
  [5] J. Barker, M.Y. Saidi, J.L. Swoyer, Electrochemical insertion properties of the novel lithium vanadium fluorophosphate, LiVPO₄F, J. Electrochem. Soc. 150 (2003) A1394-A1398.
6. [6]
  [6] H. Huang, S.C. Yin, T. Kerr, N. Taylor, L.F. Nazar, Nanostructured composites: a high capacity, fast rate Li₃V₂(PO₄)₃/carbon cathode for rechargeable lithium batteries, Adv. Mater. 14 (2002) 1525-1528.
7. [7]
  [7] S. Patoux, C. Wurm, M. Morcrette, G. Rousse, C. Masquelier, A comparative structural and electrochemical study of monoclinic Li₃Fe₂(PO₄)₃ and Li₃V₂(PO₄)₃, J. Power Sources 119-121 (2003) 278-284.
8. [8]
  [8] Y.H. Chen, Y.M. Zhao, X.N. An, et al., Preparation and electrochemical performance studies on Cr-doped Li₃V₂(PO₄)₃ as cathode materials for lithium-ion batteries, Electrochim. Acta 54 (2009) 5844-5850.
9. [9]
  [9] S. Zhang, Q. Wu, C. Deng, et al., Synthesis and characterization of Ti-Mn and Ti-Fe codoped Li₃V₂(PO₄)₃ as cathode material for lithium ion batteries, J. Power Sources 218 (2012) 56-64.
10. [10]
  [10] C. Deng, S. Zhang, S.Y. Yang, et al., Effects of Ti and Mg codoping on the electrochemical performance of Li₃V₂(PO₄)₃ cathode material for lithium ion batteries, J. Phys. Chem. C 115 (2011) 15048-15056.
11. [11]
  [11] Q.Q. Chen, X.C. Qiao, Y.B. Wang, et al., Electrochemical performance of Li_3-x-Na_xV₂(PO₄)₃/C composite cathode materials for lithium ion batteries, J. Power Sources 201 (2012) 267-273.
12. [12]
  [12] J. Barker, R.K.B. Gover, P. Burns, A. Bryan, The effect of Al substitution on the electrochemical insertion properties of the lithium vanadium phosphate, Li₃V₂(PO₄)₃, J. Electrochem. Soc. 154 (2007) A307-A313.
1. [1]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
2. [2]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
3. [3]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
4. [4]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
5. [5]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
6. [6]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
7. [7]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
8. [8]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
9. [9]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
10. [10]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
11. [11]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
12. [12]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
13. [13]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
14. [14]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
15. [15]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
16. [16]
  Hong-Tao Ji , Yu-Han Lu , Yan-Ting Liu , Yu-Lin Huang , Jiang-Feng Tian , Feng Liu , Yan-Yan Zeng , Hai-Yan Yang , Yong-Hong Zhang , Wei-Min He . Nd@C₃N₄-photoredox/chlorine dual catalyzed synthesis and evaluation of antitumor activities of 4-alkylated sulfonyl ketimines. Chinese Chemical Letters, 2025, 36(2): 110568-. doi: 10.1016/j.cclet.2024.110568
17. [17]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
18. [18]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
19. [19]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
20. [20]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(686)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nd3+-doped Li3V2(PO4)3 cathode material with high rate capability for Li-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Nd³⁺-doped Li₃V₂(PO₄)₃ cathode material with high rate capability for Li-ion batteries