Citation: Kayla J. Pyper, Taylor C. Evans, Bart M. Bartlett. Synthesis of α-SnWO₄ thin-film electrodes by hydrothermal conversion from crystalline WO₃[J]. Chinese Chemical Letters, ;2015, 26(4): 474-478. doi: 10.1016/j.cclet.2015.01.027 shu

Synthesis of α-SnWO₄ thin-film electrodes by hydrothermal conversion from crystalline WO₃

1.
Department of Chemistry University of Michigan, Ann Arbor, MI 48109-1055, USA

Corresponding author: Bart M. Bartlett,
Received Date: 22 December 2014
Available Online: 16 January 2015
Fund Project: This work was supported by a grant from a National Science Foundation (No. DMR-1253347). We thank the University of Michigan Department of Chemistry for a Research Excellence Fellowship awarded to K.J.P. and for summer undergraduate support awarded to T.C.E. (No. DMR-1253347)

Thin film electrodes of the orthorhombic form of tin tungstate (α-SnWO₄) were prepared using a hydrothermal method to convert thin films of WO₃ in aqueous SnCl₂. The pH dependence of the growth mechanism was identified by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The XRD patterns show complete conversion of WO₃(s) to SnWO₄(s) at pH 1, 4, and 7. SEM images reveal a morphology change from sponge-like platelets to sharp nanowires as the pH increases from 1 to 7. The α-SnWO₄ thin films were reddish brown in color, and display an indirect band gap of 1.9 eV by diffuse reflectance UV-vis spectroscopy. α-SnWO₄ is therefore solar-responsive, and a chopped light linear sweep voltammogram recorded under 100 mW/cm² AM1.5 simulated solar illumination in a pH 5 0.1 mol/L KP_i buffer show a visible light response for photoelectrochemical water oxidation, producing 32 mA/cm² at 1.23 V vs. RHE.
- Alpha tin tungstate,
- Hydrothermal conversion,
- Microstructure,
- Hydrothermal method
1. [1]
  [1] C. Herrero, B. Lassalle-Kaiser, W. Leibl, A.W. Rutherford, A. Aukauloo, Artificial systems related to light driven electron transfer processes in PSII, Coord. Chem. Rev. 252 (2008) 456-468.
2. [2]
  [2] Y. Ren, Z. Ma, P.G. Bruce, Ordered mesoporous metal oxides: synthesis and applications, Chem. Soc. Rev. 42 (2012) 4909-4927.
3. [3]
  [3] G.Z. Shen, P.-C. Chen, K. Ryu, C.W. Zhou, Devices and chemical sensing applications of metal oxide nanowires, J. Mater. Chem. 19 (2009) 828-839.
4. [4]
  [4] A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode, Nature 283 (1972) 37-38.
5. [5]
  [5] K. Sivula, R. Zboril, F.L. Formal, et al., Photoelectrochemical water splitting with mesoporous hematite prepared by a solution-based colloidal approach, J. Am. Chem. Soc. 132 (2010) 7436-7444.
6. [6]
  [6] P.P. González-Borrero, F. Sato, A.N. Medina, et al., Optical band-gap determination of nanostructured WO3 film, Appl. Phys. Lett. 96 (2010) 061909.
7. [7]
  [7] S.P. Berglund, D.W. Flaherty, N.T. Hahn, A.J. Bard, C.B. Mullins, Photoelectrochemical oxidation of water using nanostructured BiVO4 films, J. Phys. Chem. C 115 (2011) 3794-3802.
8. [8]
  [8] J.E. Yourey, K.J. Pyper, J.B. Kurtz, B.M. Bartlett, Chemical stability of CuWO4 for photoelectrochemical water oxidation, J. Phys. Chem. C 117 (2013) 8708-8718.
9. [9]
  [9] R. Lacomba-Perales, J. Ruiz-Fuertes, D. Errandonea, D. Martínez-García, A. Segura, Optical absorption of divalent metal tungstates: correlation between the bandgap energy and the cation ionic radius, Europhys. Lett. 83 (2008) 37002.
10. [10]
  [10] W. Jeitschko, A.W. Sleight, Synthesis, properties and crystal structure ofb-SnWO₄, Acta Cryst. B28 (1972) 3174-3178.
11. [11]
  [11] I.-S. Cho, C.H. Kwak, D.W. Kim, S. Lee, K.S. Hong, Photophysical, photoelectrochemical, and photocatalytic properties of novel SnWO₄ oxide semiconductors with narrow band gaps, J. Phys. Chem. C 113 (2009) 10647-10653.
12. [12]
  [12] H. Dong, Z. Li, Z.X. Ding, et al., Nanoplates of a-SnWO₄ and SnW₃O₉ prepared via a facile hydrothermal method and their gas-sensing property, Sens. Actuators, B: Chem. 140 (2009) 623-628.
13. [13]
  [13] G.Q. Zhu, W.X. Que, J. Zhang, P. Zhong, Photocatalytic activity of SnWO₄ and SnW₃O₉ nanostructures prepared by a surfactant-assisted hydrothermal process, Mater. Sci. Eng., B 176 (2011) 1445-1448.
14. [14]
  [14] J. Yang, W.Z. Li, J. Li, D.B. Sun, Q.Y. Chen, Hydrothermal synthesis and photoelectrochemical properties of vertically aligned tungsten trioxide (hydrate) plate-like arrays fabricated directly on FTO substrates, J. Mater. Chem. 22 (2012) 17744-17752.
15. [15]
  [15] S. Uma, J. Singh, V. Thakral, Facile room temperature ion exchange synthesis of Sn²⁺ incorporated pyrochlore-type oxides and their photocatalytic activities, Inorg. Chem. 48 (2009) 11624-11630.
16. [16]
  [16] P.G. Dickens, M.S. Whittingham, The tungsten bronzes and related compounds, Q. Rev. Chem. Soc. 22 (1968) 30-44.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of α-SnWO4 thin-film electrodes by hydrothermal conversion from crystalline WO3

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通讯作者: 陈斌, bchen63@163.com

Synthesis of α-SnWO₄ thin-film electrodes by hydrothermal conversion from crystalline WO₃