Citation: Yu-Hai Liu, Jia-Jia Shi, Dan-Qing Gao, Yun-Long Gao, Ran Guo, Xiao-Feng Ling, Shi-Fu Weng, Yi-Zhuang Xu, Isao Noda, Jin-Guang Wu. Interactions between pyridinium and Nd³⁺[J]. Chinese Chemical Letters, ;2015, 26(2): 182-186. doi: 10.1016/j.cclet.2015.01.014 shu

Interactions between pyridinium and Nd³⁺

Yu-Hai Liu ^a ,
Jia-Jia Shi ^a,b ,
Dan-Qing Gao ^a,c ,
Yun-Long Gao ^a,c ,
Ran Guo ^a ,
Xiao-Feng Ling ^d ,
Shi-Fu Weng ^a ,
Yi-Zhuang Xu ^a,e,, ,
Isao Noda ^a,f ,
Jin-Guang Wu ^a

1.
a College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
2.
b College of Chemistry and Materials, Hebei Normal University, Shijiazhuang 050016, China;
3.
c School of Postgraduate, Liaoning University of Traditional Chinese Medicine, Shenyang 11660, China;
4.
d The third school of Clinical Medicine of Peking University, Beijing, 100083, China;
e Ninhai Doubly Advanced Martial Co.
e Ninhai Doubly Advanced Martial Co., Ltd., Ninhai 315602, China;
6.
f Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA

Corresponding author: Yi-Zhuang Xu,
Received Date: 31 October 2014
Available Online: 8 December 2014
Fund Project: This project is financially supported by the National Natural Science Foundation of China (No. 51373003) (No. 51373003)Beijing Natural Science Foundation (No. 2122059). (No. 2122059)

In this paper, 2D asynchronous spectra generated by using the DAOSD approach was utilized to probe interactions between Nd³⁺ and pyridinium dissolved in aqueous solution. A series of cross peaks in the resultant 2D asynchronous spectrum confirms the occurrence of intermolecular interaction between Nd³⁺ and pyridinium. However, no coordination occurs between Nd³⁺ and pyridinium. Interaction between p electron from aromatic system and f electron from lanthanide ions account for the appearance of cross peaks in2Dasynchronous spectra.Because of the interaction, theemissionspectrumof pyridiniumexhibits a significant change when neodymium perchlorate was introduced into the system.
- 2D asynchronous spectrum,
- DAOSD,
- Nd³⁺,
- Intermolecular interaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Interactions between pyridinium and Nd3+

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通讯作者: 陈斌, bchen63@163.com

Interactions between pyridinium and Nd³⁺