Citation: Dan-Qing Gao, Xiao-Pei Li, Jia-Jia Shi, Xiao-Yan Kang, Ting-Guo Kang, Jin-Ming Xia, Xiao-Feng Ling, Shi-Fu Weng, Yi-Zhuang Xu, Isao Noda, Jin-Guang Wu. Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions[J]. Chinese Chemical Letters, ;2015, 26(2): 177-181. doi: 10.1016/j.cclet.2015.01.013 shu

Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metalions

Dan-Qing Gao ^a,b ,
Xiao-Pei Li ^b,c ,
Jia-Jia Shi ^b,d ,
Xiao-Yan Kang ^a,b ,
Ting-Guo Kang ^a,, ,
Jin-Ming Xia ^e ,
Xiao-Feng Ling ^f ,
Shi-Fu Weng ^b ,
Yi-Zhuang Xu ^b,g,, ,
Isao Noda ^b,h ,
Jin-Guang Wu ^b

1.
a School of Postgraduate, Liaoning University of Traditional Chinese Medicine, Shenyang 11660, China;
2.
b College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
3.
c Institute of Process Engineering and Chinese Academy of Sciences, Beijing 100190, China;
4.
d College of Chemistry and Materials, Hebei Normal University, Shijiazhuang 050016, China;
e Two Five Eight Health Technology Co.
e Two Five Eight Health Technology Co., Ltd, Beijing 100045, China;
6.
f The Third School of Clinical Medicine of Peking University, Beijing 100083, China;
g Ninghai Doubly Advanced Material Co.
g Ninghai Doubly Advanced Material Co., Ltd, Ninghai 315602, China;
8.
h Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA

Corresponding author: Ting-Guo Kang, Yi-Zhuang Xu,
Received Date: 30 October 2014
Available Online: 22 December 2014
Fund Project: This project is financially supported by the National Natural Science Foundation of China (No. 51373003) (No. 51373003)Beijing Natural Science Foundation (No. 2122059). (No. 2122059)

Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent paper. Spectral variation of n-π* transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in spectra. Experimental results indicate that Ca²⁺ and Al³⁺ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π* transition band, which is manifested by cross peaks in 2D asynchronous spectra.
- Ca²⁺,
- Al³⁺,
- Butanone,
- Coordination,
- 2D correlation spectroscopy
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