Citation: Xing-Yue Wei, Xing-Min Wang, Ning Li, Sheng-Ying Qin. Synthesis, O₂-binding ability and catalytic oxidation performance of cobalt(Ⅱ) complexes with dihydroxamic acid functionalized N-pivot lariat ethers[J]. Chinese Chemical Letters, ;2015, 26(1): 100-102. doi: 10.1016/j.cclet.2014.10.010 shu

Synthesis, O₂-binding ability and catalytic oxidation performance of cobalt(Ⅱ) complexes with dihydroxamic acid functionalized N-pivot lariat ethers

Xing-Yue Wei ^a,b,, ,
Xing-Min Wang ^a,b ,
Ning Li ^a,b ,
Sheng-Ying Qin ^c

1.
a College of Environmental and Biological Engineering, Chongqing Technology and Business University, Chongqing 400067, China;
2.
b Key Laboratory of Catalysis and Functional Organic Molecule, Chongqing 400067, China;
3.
c Department of Chemistry, Sichuan University, Chengdu 610064, China

Corresponding author: Xing-Yue Wei,
Received Date: 1 August 2014
Available Online: 29 September 2014
Fund Project: This work was supported by Chongqing Education Commission (No. KJ1400632). (No. KJ1400632)

Novel Co(Ⅱ) complexes with dihydroxamic acids functionalized N-pivot lariat ether CoL¹-CoL⁴ were synthesized and characterized. Their oxygenation constants (ln K_O2) and thermodynamic parameters (ΔH°, ΔS°) were measured. And their catalytic performance in oxidation of p-xylene to p-toluic acid (PTA) was investigated. The enhancement of O₂-binding and catalytic oxidation activity by the oxa aza crown ether ring of the cobalt complexes were discussed.
- Aza-crown ether,
- Hydroxamic acid,
- Cobalt complexes,
- Dioxygen affinities,
- Catalytic oxidation
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Synthesis, O₂-binding ability and catalytic oxidation performance of cobalt(Ⅱ) complexes with dihydroxamic acid functionalized N-pivot lariat ethers