Citation: Wei Wei, Ling-Xiao Song, Lin Guo. SnO₂ hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries[J]. Chinese Chemical Letters, ;2015, 26(1): 124-128. doi: 10.1016/j.cclet.2014.09.023 shu

SnO₂ hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries

Wei Wei ^a,c ,
Ling-Xiao Song ^b ,
Lin Guo ^c,,

1.
a School of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China;
2.
b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China;
3.
c School of Chemistry and Environment, Beijing University of Aeronautics & Astronautics, Beijing 100191, China

Corresponding author: Lin Guo,
Received Date: 6 August 2014
Available Online: 18 September 2014
Fund Project: This work was financially supported by the National Basic Research Program of China (Nos. 2010CB934700, 2013CB934004, 2011CB935704) (Nos. 2010CB934700, 2013CB934004, 2011CB935704)National Natural Science Foundation of China (No. 11079002). (No. 11079002)

SnO₂ hollow nanospheres were successfully synthesized via a facile one-step solvothermal method. Characterizations show that the as-prepared SnO₂ spheres are of hollow structure with a diameter at around 50 nm, and especially, the shell of the spheres is assembled by single layer SnO₂ nanocrystals. The surface area of the material reaches up to 202.5 m²/g. As an anode material for Li ion batteries, the sample exhibited improved electrochemical performance compared with commercial SnO₂ particles. After cycled at high current rate of 0.5 C, 1 C and 0.5 C for 20 cycles, respectively, the electrode can maintain a capacity of 509 mAh/g. The suitable shell thickness/diameter ratio endows the good structural stability of the material during cycling, which promises the excellent cycling performance of the electrode. The large surface area and the ultra thin shell ensure the high rate performance of the material.
- SnO₂,
- Hollow nanospheres,
- Single layer,
- Li ion batteries
1. [1]
  [1] J.S. Chen, L. Archer, X.W. Lou, SnO₂ hollow structures and TiO₂ nanosheets for lithium-ion batteries, J. Mater. Chem. 21 (2011) 9912-9924.
2. [2]
  [2] X.W. Lou, J.S. Chen, P. Chen, L.A. Archer, One-pot synthesis of carbon-coated SnO₂ nanocolloids with improved reversible lithium storage properties, Chem. Mater. 21 (2009) 2868-2874.
3. [3]
  [3] P. Meduri, E. Clark, E. Dayalan, G.U. Sumanasekera, M.K. Sunkara, Kinetically limited de-lithiation behavior of nanoscale tin-covered tin oxide nanowires, Energy Environ. Sci. 4 (2011) 1695-1699.
4. [4]
  [4] Y.M. Li, J.H. Li, Carbon-coated macroporous Sn₂P₂O₇ as anode materials for Li-ion battery, J. Phys. Chem. C 112 (2008) 14216-14219.
5. [5]
  [5] N.H. Zhao, L.C. Yang, P. Zhang, et al., Polycrystalline SnO₂ nanowires coated with amorphous carbon nanotube as anode material for lithium ion batteries, Mater. Lett. 64 (2010) 972-975.
6. [6]
  [6] Z.H. Wen, Q. Wang, Q. Zhang, J. Li, In situ growth of mesoporous SnO₂ on multiwalled carbon nanotubes: a novel composite with porous-tube structure as anode for lithium batteries, Adv. Funct. Mater. 17 (2007) 2772-2778.
7. [7]
  [7] N.H. Zhao, G.J. Wang, Y. Huang, et al., Preparation of nanowire arrays of amorphous carbon nanotube-coated single crystal SnO₂, Chem. Mater. 20 (2008) 2612- 2614.
8. [8]
  [8] Y.M. Li, X.J. Lü, J. Lu, J.H. Li, Preparation of SnO₂-nanocrystal/graphene-nanosheets composites and their lithium storage ability, J. Phys. Chem. C 114 (2010) 21770- 21774.
9. [9]
  [9] S.J. Ding, D.Y. Luan, F. Boey, et al., SnO₂ nanosheets grown on graphene sheets with enhanced lithium storage properties, Chem. Commun. 47 (2011) 7155-7157.
10. [10]
  [10] Q. Wang, Z.H. Wen, J.H. Li, Fast and reversible lithium-induced electrochemical alloying in tin-based composite oxide hierarchical microspheres assembled by nanoplate building blocks, J. Power Sources 182 (2008) 334-339.
11. [11]
  [11] H. Wang, Q.Q. Liang, W.J. Wang, et al., Preparation of flower-like SnO₂ nanostructures and their applications in gas-sensing and lithium storage, Cryst. Growth Des. 11 (2011) 2942-2947.
12. [12]
  [12] F. Wang, S. Xiao, Z. Chang, Y.Q. Yang, Y.P. Wu, Nanoporous LiNi_1/3Co_1/3Mn_1/3O₂ as an ultra-fast charge cathode material for aqueous rechargeable lithium batteries, Chem. Commun. 49 (2013) 9209-9211.
13. [13]
  [13] W. Tang, Y.Y. Hou, F.X. Wang, et al., LiMn2O4 nanotube as cathode material of second-level charge capability for aqueous rechargeable batteries, Nano Lett. 13 (2013) 2036-2040.
14. [14]
  [14] X.M. Yin, C.C. Li, M. Zhang, et al., One-step synthesis of hierarchical SnO₂ hollow nanostructures via self-assembly for high power lithium ion batteries, J. Phys. Chem. C 114 (2010) 8084-8088.
15. [15]
  [15] H.X. Yang, J.F. Qian, Z.X. Chen, X.P. Ai, Y.L. Cao, Multilayered nanocrystalline SnO₂ hollow microspheres synthesized by chemically induced self-assembly in the hydrothermal environment, J. Phys. Chem. C 111 (2007) 14067-14071.
16. [16]
  [16] D. Deng, J. Lee, Hollow core-shell mesospheres of crystalline SnO₂ nanoparticle aggregates for high capacity Li+ ion storage, Chem. Mater. 20 (2008) 1841-1846.
17. [17]
  [17] X.W. Lou,D.Deng, J.Y. Lee, L.A.Archer, PreparationofSnO₂/carboncomposite hollow spheres and their lithium storage properties, Chem. Mater. 20 (2008) 6562-6566.
18. [18]
  [18] S.J. Ding, J.S. Chen, G.G. Qi, et al., Formation of SnO₂ hollow nanospheres inside mesoporous silica nanoreactors, J. Am. Chem. Soc. 133 (2011) 21-23.
19. [19]
  [19] W. Wei, S. Gao, Z. Yang, et al., Porous SnO₂ nanocubes with controllable pore volume and their Li storage performance, RSC Adv. 4 (2014) 13250-13255.
20. [20]
  [20] Z.W. Deng, M. Chen, G.X. Gu, L. Wu, A facile method to fabricate ZnO hollow spheres and their photocatalytic property, J. Phys. Chem. B 112 (2008) 16-22.
21. [21]
  [21] H.J. Zhang, J. Wu, L.P. Zhou, D.Y. Zhang, L.M. Qi, Facile synthesis of monodisperse microspheres and gigantic hollow shells of mesoporous silica in mixed water- ethanol solvents, Langmuir 23 (2007) 1107-1113.
22. [22]
  [22] C. Li, W. Wei, S.M. Fang, et al., A novel CuO-nanotube/SnO₂ composite as the anode material for lithium ion batteries, J. Power Sources 195 (2010) 2939-2944.
23. [23]
  [23] J.F. Liang, W. Wei, D. Zhong, et al., One-step in situ synthesis of SnO₂/graphene nanocomposites and its application as an anode material for Li-ion batteries, ACS Appl. Mater. Interfaces 4 (2012) 454-459.
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SnO2 hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries

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SnO₂ hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries