Citation: Gen-Ping Yan, Xiao-Xiao He, Ke-Min Wang, Yong-Hong Wang, Jin-Quan Liu, Li-Xin Jian, Yin-Fei Mao. One pot synthesis of Ru(bpy)₃²⁺ doped graphene oxide-silica composite film for constructing high performance solid-state electrochemiluminescent sensor[J]. Chinese Chemical Letters, ;2014, 25(12): 1520-1524. doi: 10.1016/j.cclet.2014.09.021 shu

One pot synthesis of Ru(bpy)₃²⁺ doped graphene oxide-silica composite film for constructing high performance solid-state electrochemiluminescent sensor

1.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, College of Biology, Key Laboratory for Bio-nanotechnology and Molecular Engineering of Hunan Province, Hunan University, Changsha 410082, China

Corresponding author: Ke-Min Wang, Li-Xin Jian,
Received Date: 23 June 2014
Available Online: 4 September 2014
Fund Project: the project supported by Hunan Provincial Natural Science Foundation and Hunan Provincial Science and Technology Plan of China (No. 2012TT1003). (No. 20110161110016)

The Ru(bpy)₃²⁺ doped graphene oxide-silica composite film (Ru/GO-SiCF) was synthesized by one pot hydrolysis and condensation of tetraethylorthosilicate (TEOS) in the water-alcohol solution of graphene oxide and Ru(bpy)₃²⁺ at room temperature. The prepared Ru/GO-SiCF modified glassy carbon electrode (GCE) showed excellent electrochemiluminescence (ECL) behavior for the determination of tripropylamine (TPA) with high sensitivity and good stability. We expected this simple and novel material will find further application in construction of other targets sensors.
- Graphene oxide (GO)-silica composite,
- Electrochemiluminescence (ECL),
- Ru(bpy)₃²⁺,
- Sensor
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One pot synthesis of Ru(bpy)32+ doped graphene oxide-silica composite film for constructing high performance solid-state electrochemiluminescent sensor

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通讯作者: 陈斌, bchen63@163.com

One pot synthesis of Ru(bpy)₃²⁺ doped graphene oxide-silica composite film for constructing high performance solid-state electrochemiluminescent sensor