Citation: Mohammad Javaherian, Foad Kazemi, Masoumeh Ghaemi. A dicationic, podand-like, ionic liquid water system accelerated copper-catalyzed azide-alkyne click reaction[J]. Chinese Chemical Letters, ;2014, 25(12): 1643-1647. doi: 10.1016/j.cclet.2014.09.005 shu

A dicationic, podand-like, ionic liquid water system accelerated copper-catalyzed azide-alkyne click reaction

a.
a. Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz, Iran;
b.
b. Department of Chemistry, University for Advanced Studies in Basic Sciences, Iran

Corresponding author: Mohammad Javaherian,
Received Date: 8 April 2014
Available Online: 30 July 2014
Fund Project: Authors thank the Shahid Chamran University of Ahvaz for its financial support (No. 2013). (No. 2013)

In this work, an effective, task specific, dicationic, podand-like ionic liquid was synthesized and applied to improve the capability features of click reaction. Moreover, to broaden the scope and decreasing the serious limitations of preparation methods of organic azides, a simple green procedure for the preparation of alkyl azides, the fundamental starting materials in click reactions, from alcohols under solvent-free conditions and microwave irradiation has been reported, for the first time.
- Dicationic ionic liquid,
- Click chemistry,
- 1,2,3-Triazoles,
- Alkyl azides,
- Alkynes,
- Microwave irradiation
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