Citation: De-Bo Xiang, Hui-Bo Shao. Investigation of multilevel ion-pairing effect of triferrocenylmethane in organic phase[J]. Chinese Chemical Letters, ;2014, 25(10): 1379-1381. doi: 10.1016/j.cclet.2014.07.004 shu

Investigation of multilevel ion-pairing effect of triferrocenylmethane in organic phase

De-Bo Xiang ^a,b ,
Hui-Bo Shao ^a,,

1.
a Key Laboratory of Cluster Science (Ministry of Education of China), School of Chemistry, Beijing Institute of Technology, Beijing 100081, China;
b China Aviation Lithium Battery Co.
b China Aviation Lithium Battery Co., Ltd., Henan 471003, China

Corresponding author: Hui-Bo Shao,
Received Date: 22 May 2014
Available Online: 1 July 2014
Fund Project: The authors gratefully acknowledge the NSFC (No. 21173023) (No. 21173023) the 111 Project (No. B07012) in China and the TriFcM provided from professor Hua-Zhong Yu at Simon Fraser University in Canada. (No. B07012)

The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane (TriFcM) in organic phase was studied with the ‘‘thin-layer electrochemistry'' approach. Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication, which could be used to study the multilevel ion-pairing effect. Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.
- Triferrocenylmethane,
- Thin-layer electrochemistry,
- Intramolecular electronic communication,
- Multilevel ion-pairing effect
1. [1]
  [1] J.K. Ouyang, L.J. Chen, L. Xu, C.H. Wang, H.B. Yang, A new family of supramolecular multiferrocenyl rhomboids: synthesis, characterization, and their electrochemical behavior, Chin. Chem. Lett. 24 (2013) 471-474.
2. [2]
  [2] J. Xu, A. Frcic, J.A.C. Clyburne, R.A. Gossage, H.Z. Yu, Thin-layer electrochemistry of 1,3-diferrocenyl-2-buten-1-one: direct correlation between driving force and liquid/liquid interfacial electron transfer rates, J. Phys. Chem. B 108 (2004) 5742-5746.
3. [3]
  [3] M.C.P. Wang, Y.C. Li, N. Merbouh, H.Z. Yu, Thin-layer electrochemistry of ferrocenylbenzene derivatives: intramolecular electronic communication, Electrochim. Acta 53 (2008) 7720-7725.
4. [4]
  [4] D.B. Xiang, G.Y. Gao, H.B. Shao, et al., Redox behavior and ion-pairing thermodynamics of ferrocene and its derivatives in the organic phase, J. Phys. Chem. C 114 (2010) 617-621.
5. [5]
  [5] E. Dionne, T. Sultana, L. Norman, V. Toader, A. Badia, Redox-induced ion pairing of anionic surfactants with ferrocene-terminated self-assembled monolayers: faradaic electrochemistry and surfactant aggregation at the monolayer/liquid interface, J. Am. Chem. Soc. 135 (2013) 17457-17468.
6. [6]
  [6] Y. Yokota, T. Yamada, M. Kawai, Ion-pair formation between ferrocene-terminated self-assembled monolayers and counteranions studied by force measurements, J. Phys. Chem. C 115 (2011) 6775-6781.
1. [1]
  Yuhuan Meng , Long Zhang , Lequan Wang , Junming Kang , Hongbin Lu . 20 nm-ultra-thin fluorosiloxane interphase layer enables dendrite-free, fast-charging, and flexible aqueous zinc metal batteries. Chinese Chemical Letters, 2024, 35(12): 110025-. doi: 10.1016/j.cclet.2024.110025
2. [2]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
3. [3]
  Xiaxia Xing , Xiaoyu Chen , Zhenxu Li , Xinhua Zhao , Yingying Tian , Xiaoyan Lang , Dachi Yang . Polyethylene imine functionalized porous carbon framework for selective nitrogen dioxide sensing with smartphone communication. Chinese Chemical Letters, 2024, 35(9): 109230-. doi: 10.1016/j.cclet.2023.109230
4. [4]
  Kuan Deng , Fei Yang , Zhi-Qi Cheng , Bi-Wen Ren , Hua Liu , Jiao Chen , Meng-Yao She , Le Yu , Xiao-Gang Liu , Hai-Tao Feng , Jian-Li Li . Construction of wavelength-tunable DSE quinoline salt derivatives by regulating the hybridization form of the nitrogen atom and intramolecular torsion angle. Chinese Chemical Letters, 2024, 35(10): 109464-. doi: 10.1016/j.cclet.2023.109464
5. [5]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254
6. [6]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
7. [7]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
8. [8]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
9. [9]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
10. [10]
  Saadullah Khattak , Hong-Tao Xu , Jianliang Shen . Bio-electronic bandage: Self-powered performances to accelerate intestinal wound healing. Chinese Chemical Letters, 2024, 35(12): 110210-. doi: 10.1016/j.cclet.2024.110210
11. [11]
  Xinyu Tian , Jiaxiang Guo , Zeyi Li , Shihou Sheng , Tianyu Zhang , Xianfei Li , Chuandong Dou . Control over electronic structures of organic diradicaloids via precise B/O-heterocycle fusion. Chinese Chemical Letters, 2025, 36(1): 110174-. doi: 10.1016/j.cclet.2024.110174
12. [12]
  Yanjie Li , Chaoqun Qu , Siqi Meng , Jiaqi Hu , Ze Gao , Hongji Xu , Rui Gao , Ming Feng . Revealing electronic state evolution of Co(Ⅱ)/Co(Ⅲ) in CoO (111) plane during OER process through magnetic measurement. Chinese Chemical Letters, 2025, 36(3): 109872-. doi: 10.1016/j.cclet.2024.109872
13. [13]
  Shunyu Wang , Yanan Zhu , Yang Zhao , Wanli Nie , Hong Meng . Steric effects and electronic manipulation of multiple donors on S₀/S₁ transition of D_n-A emitters. Chinese Chemical Letters, 2025, 36(4): 110555-. doi: 10.1016/j.cclet.2024.110555
14. [14]
  Hang Meng , Bicheng Zhu , Ruolun Sun , Zixuan Liu , Shaowen Cao , Kan Zhang , Jiaguo Yu , Jingsan Xu . Dynamic photoluminescence switching of carbon nitride thin films for anticounterfeiting and encryption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100410-100410. doi: 10.1016/j.cjsc.2024.100410
15. [15]
  Zili Ma , Zeyu Li , Jun Lv . Shortening the formation time of oxide thin film photoelectrodes from hours to seconds. Chinese Journal of Structural Chemistry, 2025, 44(4): 100450-100450. doi: 10.1016/j.cjsc.2024.100450
16. [16]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
17. [17]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104
18. [18]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
19. [19]
  Lishan Xiong , Xinyuan Li , Xiaojie Lu , Zhendong Zhang , Yan Zhang , Wen Wu , Chenhui Wang . Inhaled multilevel size-tunable, charge-reversible and mucus-traversing composite microspheres as trojan horse: Enhancing lung deposition and tumor penetration. Chinese Chemical Letters, 2024, 35(9): 109384-. doi: 10.1016/j.cclet.2023.109384
20. [20]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(781)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142