Citation: Chen-Huan Wang, Xiao-Xing Ma, Chun Wang, Qiu-Hua Wu, Zhi Wang. Poly(vinylidene fluoride) membrane based thin film microextraction for enrichment of benzoylurea insecticides from water samples followed by their determination with HPLC[J]. Chinese Chemical Letters, ;2014, 25(12): 1625-1629. doi: 10.1016/j.cclet.2014.06.018 shu

Poly(vinylidene fluoride) membrane based thin film microextraction for enrichment of benzoylurea insecticides from water samples followed by their determination with HPLC

Chen-Huan Wang ^a,b ,
Xiao-Xing Ma ^a ,
Chun Wang ^a ,
Qiu-Hua Wu ^a,, ,
Zhi Wang ^a,,

a.
a. College of Science, Agricultural University of Hebei, Baoding 071001, China;
b.
b. No. 1 High School of Baoding, Baoding 071001, China

Corresponding author: Qiu-Hua Wu, Zhi Wang,
Received Date: 4 May 2014
Available Online: 16 June 2014
Fund Project: Financial supports from the National Natural Science Foundation of China (No. 31171698) (No. 31171698) the Innovation Research Program of Department of Education of Hebei for Hebei Provincial Universities (No. LJRC009) (No. LJRC009) and the Natural Science Foundation of Hebei (No. B2012204028) are gratefully acknowledged. (No. ZD20131033)

Thin-film microextraction (TFME), a new geometry for solid-phase microextraction, has become an attractive sample-preparation technique. Compared to other microextraction approaches, the sensitivity of this technique was enhanced without sacrificing the sampling time due to the high surface area-tovolume ratio together with the increase of extraction-phase volume. In this paper, a new TFME method based on poly(vinylidene fluoride) membrane was developed for the extraction of benzoylurea insecticides (diflubenzuron, triflumuron, hexaflumuron and teflubenzuron) from water samples followed by their determination with high performance liquid chromatography-diode array detection. Under the optimal conditions, good linearity was observed over the concentration range of 0.5-100.0 ng/mL with correlation coefficient greater than 0.9994. The limits of detection (S/N = 3) of the method for the target analytes were 0.1 ng/mL. Mean recoveries ranged from 87.7% to 103.9% with relative standard deviations lower than 6.5%. The results indicated that the developed TFMEmethod is simple, efficient, and cost effective.
- Thin film microextraction,
- Poly(vinylidene fluoride) membrane,
- Benzoylurea insecticides,
- High performance liquid chromatography
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沈阳化工大学材料科学与工程学院沈阳 110142