Citation: Wen-Jia Cai, Lin-Ping Qian, Bin Yue, He-Yong He. Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane[J]. Chinese Chemical Letters, ;2014, 25(11): 1411-1415. doi: 10.1016/j.cclet.2014.06.016 shu

Rh doping effect on coking resistance of Ni/SBA-15 catalysts in dry reforming of methane

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China

Corresponding author: Bin Yue, He-Yong He,
Received Date: 9 May 2014
Available Online: 11 June 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (21173050, 21371035). (21173050, 21371035)

A series of SBA-15 supported bimetallic Rh-Ni catalysts with different weight ratio of Rh/Ni in the range of 0-0.04 were prepared for carbon dioxide reforming of methane. The doping effect of Rh on catalytic activity as well as carbon accumulation and removal over the catalysts was studied. The characterization results indicated that the addition of a small amount of Rh promoted the reducibility of Ni particles and decreased the Ni particle size. During the dry reforming reaction, the carbon deposition was originated from CH₄ decomposition and CO disproportionation. The Rh-Ni catalyst with smallmetallic particle size inhibited the carbon formation and exhibited high efficiency in the removal of coke. In comparison with bare Ni-based catalyst, the Rh-Ni bimetallic catalysts showed high activity and stability in the dry reforming of methane.
- Methane reforming,
- Carbon dioxide,
- Rh-Ni/SBA-15,
- Carbon deposition
1. [1]
  [1] A. Shamsi, Carbon formation on Ni-MgO catalyst during reaction of methane in the presence of CO₂ and CO, Appl. Catal. A Gen. 277 (2004) 23-30.
2. [2]
  [2] S. Damyanova, B. Pawelec, K. Arishtirova, et al., MCM-41 supported PdNi catalysts for dry reforming of methane, Appl. Catal. B Environ. 92 (2009) 250-261.
3. [3]
  [3] M.L. Zhang, S.F. Ji, L.H. Hu, et al., Structural characterization of highly stable Ni/SBA-15 catalyst and its catalytic performance for methane reforming with CO₂, Chin. J. Catal. 27 (2006) 777-782.
4. [4]
  [4] C.K. Shi, P. Zhang, Effect of a second metal (Y, K, Ca, Mn or Cu) addition on the carbon dioxide reforming of methane over nanostructured palladium catalysts, Appl. Catal. B Environ. 115 (2012) 190-200.
5. [5]
  [5] M.C.J. Bradford, M.A. Vannice, CO₂ reforming of CH₄, Catal. Rev. Sci. Eng. 41 (1999) 1-42.
6. [6]
  [6] M.C.J. Bradford, M.A. Vannice, Catalytic reforming of methane with carbon dioxide over nickel catalysts. 1. Catalyst characterization and activity, Appl. Catal. A Gen. 142 (1996) 73-96.
7. [7]
  [7] L. Qian, Z.F. Yan, Study on the reaction mechanism for carbon dioxide reforming of methane over supported nickel catalyst, Chin. Chem. Lett. 14 (2003) 1081-1084.
8. [8]
  [8] V.Y. Bychkov, Y.P. Tyulenin, A.A. Firsova, et al., Carbonization of nickel catalysts and its effect on methane dry reforming, Appl. Catal. A Gen. 453 (2013) 71-79.
9. [9]
  [9] L. Guczi, G. Stefler, O. Geszti, et al., Methane dry reforming with CO₂: a study on surface carbon species, Appl. Catal. A Gen. 375 (2010) 236-246.
10. [10]
  [10] D.P. Liu, W.N.E. Cheo, Y.W.Y. Lim, et al., A comparative study on catalyst deactivation of nickel and cobalt incorporated MCM-41 catalysts modified by platinum in methane reforming with carbon dioxide, Catal. Today 154 (2010) 229-236.
11. [11]
  [11] J.C.S. Wu, H.C. Chou, Bimetallic Rh-Ni/BN catalyst for methane reforming with CO₂, Chem. Eng. J. 148 (2009) 539-545.
12. [12]
  [12] Z.Y. Hou, T. Yashima, Small amounts of Rh-promoted Ni catalysts for methane reforming with CO₂, Catal. Lett. 89 (2003) 193-197.
13. [13]
  [13] D.Y. Zhao, J.L. Feng, Q.S. Huo, et al., Triblock copolymer syntheses of mesoporous silica with periodic 50-300 angstrom pores, Science 279 (1998) 548-552.
14. [14]
  [14] W.Z. Weng, C.R. Luo, J.J. Huang, Y.Y. Liao, H.L. Wan, Comparative study on the mechanisms of partial oxidation of methane to syngas over rhodium supported on SiO₂ and γ-Al₂O₃, Top. Catal. 22 (2003) 87-93.
15. [15]
  [15] A. Le Valant, N. Bion, F. Can, D. Duprez, F. Epron, Preparation and characterization of bimetallic Rh-Ni/Y₂O₃-Al₂O₃ for hydrogen production by raw bioethanol steam reforming: influence of the addition of nickel on the catalyst performances and stability, Appl. Catal. B Environ. 97 (2010) 72-81.
16. [16]
  [16] S. Gaur, D.J. Haynes, J.J. Spivey, Rh, Ni, and Ca substituted pyrochlore catalysts for dry reforming of methane, Appl. Catal. A Gen. 403 (2011) 142-151.
17. [17]
  [17] V.L. Barrio, P.L. Arias, J.F. Cambra, et al., Aromatics hydrogenation on silicaalumina supported palladium-nickel catalysts, Appl. Catal. A Gen. 242 (2003) 17-30.
18. [18]
  [18] M. Ocsachoque, F. Pompeo, G. Gonzalez, Rh-Ni/CeO2-Al₂O₃ catalysts for methane dry reforming, Catal. Today 172 (2011) 226-231.
19. [19]
  [19] M. Garcia-Dieguez, I.S. Pieta, M.C. Herrera, M.A. Larrubia, L.J. Alemany, Rh-Ni nanocatalysts for the CO₂ and CO₂ + H₂O reforming of methane, Catal. Today 172 (2011) 136-142.
20. [20]
  [20] H. Anita, G. Stefler, O. Geszti, et al., Methane dry reforming with CO₂ on CeZr-oxide supported Ni, NiRh and NiCo catalysts prepared by sol-gel technique: relationship between activity and coke formation, Catal. Today 169 (2011) 102-111.
21. [21]
  [21] U. Oemar, K. Hidajat, S. Kawi, Role of catalyst support over PdO-NiO catalysts on catalyst activity and stability for oxy-CO₂ reforming of methane, Appl. Catal. A: Gen. 402 (2011) 176-187.
22. [22]
  [22] I. Luisetto, S. Tuti, E. Di Bartolomeo, Co, Ni supported on CeO2 as selective bimetallic catalyst for dry reforming of methane, Int. J. Hydrogen Energy 37 (2012) 15992-15999.
23. [23]
  [23] J.Z. Luo, Z.L. Yu, C.F. Ng, C.T. Au, CO₂/CH₄ reforming over Ni-La₂O₃/5A: an investigation on carbon deposition and reaction steps, J. Catal. 194 (2000) 198-210.
24. [24]
  [24] N.A. Pechimuthu, K.K. Pant, S.C. Dhingra, Deactivation studies over Ni-K/CeO2- Al₂O₃ catalyst for dry reforming of methane, Ind. Eng. Chem. Res. 46 (2007) 1731- 1736.
25. [25]
  [25] M.A. Goula, A.A. Lemonidou, A.M. Efstathiou, Characterization of carbonaceous species formed during reforming of CH₄ with CO₂ over Ni/CaO-Al₂O₃ catalysts studied by various transient techniques, J. Catal. 161 (1996) 626-640.
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