Citation: Bao-He Wang, Jin-Shi Dong, Shuang Chen, Li-Li Wang, Jing Zhu. ZnCl₂-modified ion exchange resin as an efficient catalyst for the bisphenol-A production[J]. Chinese Chemical Letters, ;2014, 25(11): 1423-1427. doi: 10.1016/j.cclet.2014.06.004 shu

ZnCl₂-modified ion exchange resin as an efficient catalyst for the bisphenol-A production

1.
Key Laboratory for Green Chemical Technology of Ministry of Education, Research and Development Center of Petrochemical Technology, Tianjin University, Tianjin 300072, China

Corresponding author: Jing Zhu,
Received Date: 1 April 2014
Available Online: 29 May 2014

A ZnCl₂-modified ion exchange resin as the catalyst for bisphenol-A synthesis was prepared by the ion exchange method. Scanning electron microscope (SEM), Fourier transform infrared spectrophotometer (FT-IR), thermo gravimetric analyzer (TGA) and pyridine adsorbed IR were employed to characterize the catalyst. As a result, the modified catalyst showed high acidity and good thermal stability. Zn²⁺ coordinated with a sulfonic acid group to form a stable active site, which effectively decreased the deactivation caused by the degradation of sulfonic acid. Thus the prepared catalyst exhibited excellent catalytic activity, selectivity and stability compared to the unmodified counterpart.
- Zinc chloride,
- Ion exchange resin,
- Modification,
- Bisphenol-A
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沈阳化工大学材料科学与工程学院沈阳 110142

ZnCl2-modified ion exchange resin as an efficient catalyst for the bisphenol-A production

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通讯作者: 陈斌, bchen63@163.com

ZnCl₂-modified ion exchange resin as an efficient catalyst for the bisphenol-A production