Citation: Gui-Jiang Zhang, Xin Zhou, Xiao-Huan Zang, Zhi Li, Chun Wang, Zhi Wang. Analysis of nitrobenzene compounds in water and soil samples by graphene composite-based solid-phase microextraction coupled with gas chromatography-mass spectrometry[J]. Chinese Chemical Letters, ;2014, 25(11): 1449-1454. doi: 10.1016/j.cclet.2014.05.049 shu

Analysis of nitrobenzene compounds in water and soil samples by graphene composite-based solid-phase microextraction coupled with gas chromatography-mass spectrometry

1.
Department of Chemistry, College of Science, Agricultural University of Hebei, Baoding 071001, China

Corresponding author: Zhi Wang,
Received Date: 18 March 2014
Available Online: 26 May 2014
Fund Project: Financial support from the National Natural Science Foundation of China (No. 31171698) (No. 31171698) the Innovation Research Group Program of Department of Education of Hebei for Hebei Provincial Universities (No. LJRC009) (No. LJRC009)the Natural Science Foundation of Hebei Province (No. B2012204028) are gratefully acknowledged. (No. B2012204028)

In this work, solid-phase microextraction coupled with gas chromatography-mass spectrometry was developed to determine trace levels of nitrobenzene compounds in water and soil samples. Graphene was chosen as the extractionmaterial and its composite was coated on a stainless steel wire through sol- gel technique for the solid phase microextraction. The key parameters influencing the extraction efficiency were optimized. Under the optimal conditions, the linearity for the compounds was observed in the range of 0.02-15.0 μg/L for water samples, and 0.2-60.0 μg/kg for soil samples, with the correlation coefficients (r) of 0.9966-0.9987. The limits of detection of the method were 0.0025-0.005 μg/L for water samples, and 0.02-0.04 μg/kg for soil samples. The recoveries for the spiked samples were in the range of 72.0%-113.2%, and the precision, expressed as the relative standard deviations, was less than 12.1%.
- Graphene,
- Solid-phase microextraction,
- Nitrobenzene compounds,
- Gas chromatography-mass spectrometry
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沈阳化工大学材料科学与工程学院沈阳 110142