Citation: Jie He, Jia-Sheng Yu, Yan-Jie Hou, Zuo-Yi Zhu, Zhong-Ping Huang, Mu-Hua Wang, Nai-Fei Zhong, Yan Zhu. Determination of iminodiacetic acid in the glyphosate by ion chromatography[J]. Chinese Chemical Letters, ;2014, 25(10): 1392-1394. doi: 10.1016/j.cclet.2014.05.036 shu

Determination of iminodiacetic acid in the glyphosate by ion chromatography

Jie He ^a,b ,
Jia-Sheng Yu ^a,b ,
Yan-Jie Hou ^c ,
Zuo-Yi Zhu ^a,b ,
Zhong-Ping Huang ^a,b ,
Mu-Hua Wang ^d ,
Nai-Fei Zhong ^e ,
Yan Zhu ^a,b,,

1.
a Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou 310028, China;
2.
b Zhejiang Provincial Key Laboratory of Health Risk Appraisal for Trace Toxic Chemicals, Zhejiang University, Hangzhou 310028, China;
3.
c School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China;
4.
d Department of Chemistry, Lishui University, Lishui 323000, China;
5.
e Thermofisher Scientific, Hangzhou 310028, China

Corresponding author: Yan Zhu,
Received Date: 26 March 2014
Available Online: 29 April 2014
Fund Project: This research was financially supported by the National Important Project on Science Instrument (No. 2012YQ09022903) (No. 2012YQ09022903) Zhejiang Provincial Natural Science Foundation of China (No. Y4110532) (No. Y4110532)

In this paper, a simple method based on ion chromatography (IC) with conductivity detection was developed for the determination of iminodiacetic acid (IDA) in the herbicide of glyphosate. Under optimized chromatographic conditions, good linear relationship, sensitivity and reproducibility were obtained. The detection limit (LOD) for IDA obtained by injecting 25 μL of sample was 31.8 μg/L (S/ N = 3). Relative standard deviation (RSD) of repeated analysis for the peak areas was less than 1.53% (n = 6). A spiking study was performed with satisfactory recoveries between 92.8% and 103.6%. It was confirmed that this method could be applied in glyphosate products.
- Ion chromatography,
- Iminodiacetic acid (IDA),
- Glyphosate
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