Citation: Li-Qing Ma, Hao Chen, Yong-Min Guo, Bao-Zong Li, Yi Li. Preparation of single-handed helical phenolic resin nanofibers using a supramolecular templating method[J]. Chinese Chemical Letters, ;2014, 25(10): 1363-1366. doi: 10.1016/j.cclet.2014.05.035 shu

Preparation of single-handed helical phenolic resin nanofibers using a supramolecular templating method

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Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Bao-Zong Li,
Received Date: 14 March 2014
Available Online: 30 April 2014
Fund Project: This work was supported by the Natural Science Foundation of Jiangsu Province (No. BK2011354) (No. BK2011354) the Priority Academic Program Development of Jiangsu High Education Institutions (PAPD, No. YX10900114) (PAPD, No. YX10900114)

Single-handed helical phenolic resin nanofibers were synthesized through a supramolecular templating approach using the supramolecular self-assemblies of a pair of chiral low-molecular-weight amphiphiles as the templates and 2,4-dihydroxybenzoic acid and formaldehyde as the precursors. The phenolic resin nanofibers were characterized using field-emission scanning electron microscopy, transmission electron microscopy and diffused reflection circular dichroism. The results indicated that the chirality of the supramolecular self-assemblies was successfully transferred to the phenolic resin nanofibers. The left-and right-handed helical phenolic resin nanofibers exhibited opposite optical activity.
- Supramolecular template,
- Chirality,
- Phenolic resins,
- Nanofibers
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沈阳化工大学材料科学与工程学院沈阳 110142