Citation: Feng-Jiao Chen, Chang-Wang Shao, Min-Nan Zhao, Zhao-Sheng Bu, Yan Zhang, Xiao-Nan Dai, Guo-Wei Zhou. Controllable synthesis and photocatalytic activities of rod-shaped mesoporous titanosilicate composites with varied aspect ratios[J]. Chinese Chemical Letters, ;2014, 25(6): 962-966. doi: 10.1016/j.cclet.2014.05.034 shu

Controllable synthesis and photocatalytic activities of rod-shaped mesoporous titanosilicate composites with varied aspect ratios

1.
a Key Laboratory of Fine Chemicals in Universities of Shandong, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Ji'nan 250353, China;
2.
b School of Chemical Engineering and Environment, Weifang University of Science and Technology, Weifang 262700, China

Corresponding author: Guo-Wei Zhou,
Received Date: 3 March 2014
Available Online: 23 April 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 20976100, 51372124) (Nos. 20976100, 51372124) the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province (No. 201207) (Nos. ZR2010BM013, ZR2011BQ009)

Rod-shaped mesoporous titanosilicate composites (RMTSs) with controllable aspect ratios (ARs) were fabricated using cetyltrimethylammonium bromide (CTAB) and ammonium hydroxide (NH4OH) at a continuous stirring rate, resulting in ARs ranging from 1 to 5. Slowing the stirring rate or increasing the concentration of CTAB mainly impacted the length growth, whereas NH4OH affected the width growth. Photocatalytic activity studies revealed that the length of RMTSs played a more significant role than the width at lower ARs in their photocatalytic activity.
- Titanosilicate,
- Aspect ratio,
- Growth direction,
- Photocatalytic activity
1. [1]
  [1] Y. Pu, G.L. Zhu, B.S. Ge, et al., Photocurrent generation by recombinant allophycocyanin trimer multilayer on TiO₂ electrode, Chin. Chem. Lett. 24 (2013) 163-166.
2. [2]
  [2] S. Abdolmohammadi, Simple route to indeno [1,2-b] quinoline derivatives via a coupling reaction catalyzed by TiO₂ nanoparticles, Chin. Chem. Lett. 24 (2013) 318-320.
3. [3]
  [3] W. Li, Z. Wu, J. Wang, A.A. Elzatahry, D. Zhao, A perspective on mesoporous TiO₂ materials, Chem. Mater. 26 (2014) 289-298.
4. [4]
  [4] T. Lin, X. Zhang, R. Li, T. Bai, S.Y. Yang, Synergistic catalysis of isolated Fe³⁺ and Fe₂O₃ on FeO_x/HZSM-5 catalysts for Friedel-Crafts benzylation of benzene, Chin. Chem. Lett. 22 (2011) 639-642.
5. [5]
  [5] N. Murakami, S. Katayama, M. Nakamura, T. Tsubota, T. Ohno, Dependence of photocatalytic activity on aspect ratio of shape-controlled rutile titanium (IV) oxide nanorods, J. Phys. Chem. C 115 (2010) 419-424.
6. [6]
  [6] X.J. Wu, Y.Y. Jiang, D.S. Xu, A unique transformation route for synthesis of rodlike hollow mesoporous silica particles, J. Phys. Chem. C 115 (2011) 11342-11347.
7. [7]
  [7] W. Li, Y.H. Deng, Z.X. Wu, et al., Hydrothermal etching assisted crystallization: a facile route to functional yolk-shell titanate microspheres with ultrathin nanosheets-assembled double shells, J. Am. Chem. Soc. 133 (2011) 15830-15833.
8. [8]
  [8] W. Li, J.P. Yang, Z.X. Wu, et al., A versatile kinetics-controlled coating method to construct uniform porous TiO₂ shells for multifunctional core-shell structures, J. Am. Chem. Soc. 134 (2012) 11864-11867.
9. [9]
  [9] D.X. Liu, M.Z. Yates, Fabrication of size-tunable TiO₂ tubes using rod-shaped calcite templates, Langmuir 23 (2007) 10333-10341.
10. [10]
  [10] K. Zimny, C. Carteret, M. Stébé, J. Blin, Multitechnique investigation of mesoporous titanosilicate materials prepared from both the self-assembly and the liquid crystal mechanisms, J. Phys. Chem. C 115 (2011) 8684-8692.
11. [11]
  [11] H. Jin, Z. Liu, T. Ohsuna, et al., Control of morphology and helicity of chiral mesoporous silica, Adv. Mater. 18 (2006) 593-596.
12. [12]
  [12] C. Kresge, M. Leonowicz, W. Roth, J. Vartuli, J. Beck, Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism, Nature 359 (1992) 710-712.
13. [13]
  [13] Z.L. Yang, J.L. Li, C.L. Zhang, et al., Two-dimensional mesoporous materials: from fragile coatings to flexible membranes, Chin. Chem. Lett. 24 (2013) 89-92.
14. [14]
  [14] Y. Liu, R.O. Claus, Blue light emitting nanosized TiO₂ colloids, J. Am. Chem. Soc. 119 (1997) 5273-5274.
15. [15]
  [15] G. Li, X. Zhao, Characterization and photocatalytic properties of titaniuμ-containing mesoporous SBA-15, Ind. Eng. Chem. Res. 45 (2006) 3569-3573.
16. [16]
  [16] H.M. Abdelaal, Fabrication of hollow silica microspheres utilizing a hydrothermal approach, Chin. Chem. Lett. 25 (2014) 627-629.
17. [17]
  [17] G.N. Shao, G. Elineema, D.V. Quang, et al., Two step synthesis of a mesoporous titania-silica composite from titanium oxychloride and sodium silicate, Powder Technol. 217 (2012) 489-496.
18. [18]
  [18] N.S.M. Yusof, M.N. Khan, M. Ashokkumar, Characterization of the structural transitions in CTAB micelles using fluorescein isothiocyanate, J. Phys. Chem. C 116 (2012) 15019-15027.
19. [19]
  [19] Z. Jin, X. Wang, X. Cui, Synthesis and morphological investigation of ordered SBA-15-type mesoporous silica with an amphiphilic triblock copolymer template under various conditions, Colloids Surf. A 316 (2008) 27-36.
20. [20]
  [20] W. Stöber, A. Fink, E. Bohn, Controlled growth of monodisperse silica spheres in the micron size range, J. Colloid Interface Sci. 26 (1968) 62-69.
21. [21]
  [21] P. Horcajada, A. Ramila, J. Perez-Pariente, M. Vallet-Regi, Influence of pore size of MCM-41 matrices on drug delivery rate, Microporous Mesoporous Mater. 68 (2004) 105-109.
22. [22]
  [22] M. Kruk, M. Jaroniec, A. Sayari, Adsorption study of surface and structural properties of MCM-41 materials of different pore sizes, J. Phys. Chem. B 101 (1997) 583-589.
23. [23]
  [23] A.J. Wang, T. Kabe, Fine-tuning of pore size of MCM-41 by adjusting the initial pH of the synthesis mixture, Chem. Commun. (1999) 2067-2068.
24. [24]
  [24] L. Coppola, R. Gianferri, I. Nicotera, C. Oliviero, G.A. Ranieri, Structural changes in CTAB/H₂O mixtures using a rheological approach, Phys. Chem. Chem. Phys. 6 (2004) 2364-2372.
25. [25]
  [25] N.C. Das, H. Cao, H. Kaiser, et al., Shape and size of highly concentrated micelles in CTAB/NaSal solutions by small angle neutron scattering (SANS), Langmuir 28 (2012) 11962-11968.
26. [26]
  [26] T. Bellini, N.A. Clark, V. Degiorgio, F. Mantegazza, G. Natale, Light-scattering measurement of the nematic correlation length in a liquid crystal with quenched disorder, Phys. Rev. E 57 (1998) 2996-3006.
27. [27]
  [27] H.J. Yun, H. Lee, J.B. Joo, W. Kim, J. Yi, Influence of aspect ratio of TiO₂ nanorods on the photocatalytic decomposition of formic acid, J. Phys. Chem. C 113 (2009) 3050-3055.
1. [1]
  Yueying Wang , Jianming Xiong , Linwei Xin , Yuanyuan Li , He Huang , Wenjun Miao . Photosensitizer-synergized g-carbon nitride nanosheets with enhanced photocatalytic activity for eradicating drug-resistant bacteria and promoting wound healing. Chinese Chemical Letters, 2025, 36(4): 110003-. doi: 10.1016/j.cclet.2024.110003
2. [2]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
3. [3]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
4. [4]
  Jiayi Guo , Liangxiong Ling , Qinwei Lu , Yi Zhou , Xubiao Luo , Yanbo Zhou . Degradation of chloroxylenol by CoS_x activated peroxomonosulfate: Role of cobalt-sulfur ratio. Chinese Chemical Letters, 2025, 36(4): 110380-. doi: 10.1016/j.cclet.2024.110380
5. [5]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
6. [6]
  Ali Dai , Zhiguo Zheng , Liusheng Duan , Jian Wu , Weiming Tan . Small molecule chemical scaffolds in plant growth regulators for the development of agrochemicals. Chinese Chemical Letters, 2025, 36(4): 110462-. doi: 10.1016/j.cclet.2024.110462
7. [7]
  Xinghong Cai , Qiang Yang , Yao Tong , Lanyin Liu , Wutang Zhang , Sam Zhang , Min Wang . AlO₂: A novel two-dimensional material with a high negative Poisson's ratio for the adsorption of volatile organic compounds. Chinese Chemical Letters, 2025, 36(2): 109586-. doi: 10.1016/j.cclet.2024.109586
8. [8]
  Yang Liu , Yan Liu , Kaiyin Yang , Zhiruo Zhang , Wenbo Zhang , Bingyou Yang , Hua Li , Lixia Chen . A selective HK2 degrader suppresses SW480 cancer cell growth by degrading HK2. Chinese Chemical Letters, 2024, 35(8): 109264-. doi: 10.1016/j.cclet.2023.109264
9. [9]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
10. [10]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
11. [11]
  Chuyu Huang , Zhishan Liu , Linping Zhao , Zuxiao Chen , Rongrong Zheng , Xiaona Rao , Yuxuan Wei , Xin Chen , Shiying Li . Metal-coordinated oxidative stress amplifier to suppress tumor growth combined with M2 macrophage elimination. Chinese Chemical Letters, 2024, 35(12): 109696-. doi: 10.1016/j.cclet.2024.109696
12. [12]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
13. [13]
  Jiayi Lu , Yizhang Li , Hao Jiang , Zhiwen Zhu , Fengru Zheng , Qiang Sun . Preparing sub-monolayer metals with continuous coverage spread for high-throughput growth of metal-organic frameworks. Chinese Chemical Letters, 2025, 36(3): 110394-. doi: 10.1016/j.cclet.2024.110394
14. [14]
  Guangyao Wang , Zhitong Xu , Ye Qi , Yueguang Fang , Guiling Ning , Junwei Ye . Electrospun nanofibrous membranes with antimicrobial activity for air filtration. Chinese Chemical Letters, 2024, 35(10): 109503-. doi: 10.1016/j.cclet.2024.109503
15. [15]
  Ting Wang , Xin Yu , Yaqiang Xie . Unlocking stability: Preserving activity of biomimetic catalysts with covalent organic framework cladding. Chinese Chemical Letters, 2024, 35(6): 109320-. doi: 10.1016/j.cclet.2023.109320
16. [16]
  Fangping Yang , Jin Shi , Yuansong Wei , Qing Gao , Jingrui Shen , Lichen Yin , Haoyu Tang . Mixed-charge glycopolypeptides as antibacterial coatings with long-term activity. Chinese Chemical Letters, 2025, 36(2): 109746-. doi: 10.1016/j.cclet.2024.109746
17. [17]
  Chong Liu , Ling Li , Jiahui Gao , Yanwei Li , Nazhen Zhang , Jing Zang , Cong Liu , Zhaopei Guo , Yanhui Li , Huayu Tian . The study of antibacterial activity of cationic poly(β-amino ester) regulating by amphiphilic balance. Chinese Chemical Letters, 2025, 36(2): 110118-. doi: 10.1016/j.cclet.2024.110118
18. [18]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
19. [19]
  Ruonan Yang , Jiajia Li , Dongmei Zhang , Xiuqi Zhang , Xia Li , Han Yu , Zhanhu Guo , Chuanxin Hou , Gang Lian , Feng Dang . Grain-refining Co_0.85Se@CNT cathode catalyst with promoted Li₂O₂ growth kinetics for lithium-oxygen batteries. Chinese Chemical Letters, 2024, 35(12): 109595-. doi: 10.1016/j.cclet.2024.109595
20. [20]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(730)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142