Citation: Xiao-Dong Xia, Tian-Lun Wang, Xiao-Yuan Yuan. Tuning plasmon absorption of unmodified silver nanoplates for sensitive and selective detection of copper ions by introduction of ascorbate[J]. Chinese Chemical Letters, ;2014, 25(10): 1403-1406. doi: 10.1016/j.cclet.2014.05.033 shu

Tuning plasmon absorption of unmodified silver nanoplates for sensitive and selective detection of copper ions by introduction of ascorbate

1.
Key Laboratory of Theoretical Chemistry and Molecular Simulation, Minister of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

Corresponding author: Xiao-Dong Xia,
Received Date: 24 February 2014
Available Online: 29 April 2014
Fund Project: This work is supported by the National Natural Science Foundation of China (No. 21375036) (No. 21375036)

Silver nanoplates as novel optical sensors for Cu²⁺ detection have been demonstrated. Silver nanoplates are synthesized via previous H₂O₂-NaBH₄ cyclic oxidation-reduction reactions. With introduction of ascorbate as mild reductants, Cu²⁺ ions are reduced into Cu⁺ and the Cu⁺ is further reduced to Cu, which is deposited on the surface of the silver nanoplates. The deposition of the Cu on the surface of the silver nanoplates allows a significant red-shift of their plasmon absorption. Therefore, trace Cu²⁺ can be detected. The shift of the plasmon absorption wavelength of silver nanoplates is proportional to the Cu²⁺ concentration over a range of 40-340 μmol L^-1 with a limit of detection of 9.0 μmol L^-1. Moreover, such silver nanoplate-based optical sensors provide good selectivity for Cu²⁺ detection, and most other metal ions do not disturb its detection. Moreover, the practicality of the proposed sensor was tested. This Cu²⁺ assay is advantageous in its simplicity, selectivity, and cost-effectiveness.
- Silver nanoplate,
- Plasmon absorption,
- Wavelength shift,
- Optical sensor,
- Copper ions,
- Ascorbate
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