Citation: Long Kang, Shi-Xiong Sun, Ling-Bin Kong, Jun-Wei Lang, Yong-Chun Luo. Investigating metal-organic framework as a new pseudo-capacitive material for supercapacitors[J]. Chinese Chemical Letters, ;2014, 25(6): 957-961. doi: 10.1016/j.cclet.2014.05.032 shu

Investigating metal-organic framework as a new pseudo-capacitive material for supercapacitors

1.
a State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;
2.
b Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China

Corresponding author: Ling-Bin Kong,
Received Date: 17 February 2014
Available Online: 22 April 2014

A new application ofmetal organic framework (MOF) as a pseudo-capacitive material for supercapacitors is investigated. To this end, a simple nickel-based MOF, formulated Ni₃(btc)₂•12H₂O, is synthesized via a hydrothermal reaction. As an electro-active material, such nickel-based MOF exhibits superior pseudocapacitive behavior in KOH aqueous electrolyte with a high specific capacitance of 726 F g^-1. Also, it displays good electrochemical stability with 94.6% of the initial capacitance over consecutive 1000 cycles. In addition, a simple asymmetric supercapacitor with a high energy density of 16.5 Wh kg^-1 is successfully built using the nickel-based MOF as positive electrode and commercial activated carbon as negative electrode in KOH electrolyte.
- Supercapacitor,
- Pseudo-capacitive material,
- Metal-organic framework,
- Energy storage
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1.
沈阳化工大学材料科学与工程学院沈阳 110142