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Citation: Tao Zheng, Min Ren, Song-Song Bao, Li-Min Zheng. M2(pbtcH)(phen)2(H2O)2 [M(II)=Co, Ni]：Mixed-ligated metal phosphonates based on 5-phosphonatophenyl-1,2,4-tricarboxylic acid showing double chain structures[J]. Chinese Chemical Letters, ;2014, 25(6): 835-838. doi: 10.1016/j.cclet.2014.05.005 shu

M2(pbtcH)(phen)2(H2O)2 [M(II)=Co, Ni]：Mixed-ligated metal phosphonates based on 5-phosphonatophenyl-1,2,4-tricarboxylic acid showing double chain structures

  • 1.

    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

  • Corresponding author: Li-Min Zheng, 
  • Received Date: 17 March 2014
    Available Online: 28 April 2014

    Fund Project: Financial supports by the National Basic Research Program of China (No. 2013CB922102) (No. 2013CB922102)the NSF of Jiangsu Province of China (No. BK2009009) are acknowledged. (No. BK2009009)

  • Two new mixed-ligated metal phosphonates, M2(pbtcH)(phen)2(H2O)2 [M(II)=Co (1), Ni (2)] (pbtcH5=5-phosphonatophenyl-1,2,4-tricarboxylic acid, phen=1,1'-phenanthroline), have been synthesized and characterized. Both show one-dimensional double chain structures, where the M(phen)(H2O) moieties are chelated and bridged by pbtcH4- through the carboxylate and phosphonate oxygen atoms. The chains are connected by hydrogen bonding interactions and π-π stacking, forming a three-dimensional supramolecular structure. The IR and magnetic properties of the two compounds are also investigated.
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