Citation:
Rui Chen, Tie-Hong Chen. Facile synthesis of coordination polymer nanocubes and their conversion into mesoporous single crystal-like Y2O3 nanocubes[J]. Chinese Chemical Letters,
;2014, 25(6): 869-873.
doi:
10.1016/j.cclet.2014.04.030
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Mesoporous single crystal-like Y2O3 nanocubes have been prepared through a coordination-based selfassembly process. Firstly, a uniform nanocube-like Y-lysine precursor was simply prepared with hydrothermal treatment. After the simple thermal treatment process, nanocube-shaped yttrium oxides with the morphology inherited from the Y-lysine precursor were successfully prepared. The phase, morphology, size and crystalline structure were well characterized by XRD, SEM and TEM. N2 adsorption-desorption demonstrates the mesoporous characteristics of the Y2O3 nanocubes, showing a relatively high surface area of 60 m2/g.
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Keywords:
- Mesoporous,
- Y2O3,
- Single crystal,
- Nanocube,
- Template-free
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[1]
[1] L.H. Chen, X.Y. Li, J.C. Rooke, et al., Hierarchically structured zeolites: synthesis, mass transport properties and applications, J. Mater. Chem. 22 (2012) 17381-17403.
-
[2]
[2] L.N. Jin, Q. Liu, W.Y. Sun, Room temperature solution-phase synthesis of flowerlike nanostructures of [Ni3(BTC)2•12H2O] and their conversion to porous NiO, Chin. Chem. Lett. 24 (2013) 663-667.
-
[3]
[3] Y.F. Shi, Y. Wan, D.Y. Zhao, Ordered mesoporous non-oxide materials, Chem. Soc. Rev. 40 (2011) 3854-3878.
-
[4]
[4] P.D. Yang, D.Y. Zhao, D.I. Margolese, B.F. Chmelka, G.D. Stucky, Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework, Chem. Mater. 11 (1999) 2813-2826.
-
[5]
[5] A.M. Spokoyny, D. Kim, A. Sumrein, C.A. Mirkin, Infinite coordination polymer nano-and microparticle structures, Chem. Soc. Rev. 38 (2009) 1218-1227.
-
[6]
[6] M.Y. Masoomi, A. Morsali, Applications of metal-organic coordination polymers as precursors for preparation of nano-materials, Coord. Chem. Rev. 256 (2012) 2921-2943.
-
[7]
[7] J. Wang, J. Wu, J. Lin, et al., Application of Y2O3:Er3+ nanorods in dye-sensitized solar cells, ChemSusChem 5 (2012) 1307-1312.
-
[8]
[8] J.B. Ma, Z.C. Wang, M. Schlangen, S.G. He, H. Schwarz, Thermal reactions of YAlO3 with methane: increasing the reactivity of Y2O3 and the selectivity of Al2O3, Angew. Chem. Int. Ed. 51 (2012) 5991-5994.
-
[9]
[9] Q. Dai, M.E. Foley, C.J. Breshike, A. Lita, G.F. Strouse, Ligand-passivated Eu:Y2O3 nanocrystals as a phosphor for white light emitting diodes, J. Am. Chem. Soc. 133 (2011) 15475-15486.
-
[10]
[10] Y.J.O. Asencios, C.B. Rodella, E.M. Assaf, Oxidative reforming of model biogas over NiO-Y2O3-ZrO2 catalysts, Appl. Catal. B 132-133 (2013) 1-12.
-
[11]
[11] M.H. Abadi, M.N. Hamidon, A.H. Shaari, et al., Characterization of mixed xWO3(1-x)Y2O3 nanoparticle thick film for gas sensing application, Sensors (Basel) 10 (2010) 5074-5089.
-
[12]
[12] Y. Zhang, S. Pan, X. Teng, Y. Luo, G. Li, Bifunctional magnetic-luminescent nanocompositesY2O3/Tb nanorods on the surface of iron oxidesilica core-shell nanostructures, J. Phys. Chem. C 112 (2008) 9623-9626.
-
[13]
[13] Y.B. Mao, J.Y. Huang, R. Ostroumov, K.L. Wang, J.P. Chang, Synthesis and luminescence properties of erbiuμ-doped Y2O3 nanotubes, J. Phys. Chem. C 112 (2008) 2278-2285.
-
[14]
[14] G. Jia, M. Yang, Y.H. Song, H.P. You, H.J. Zhang, General and facile method to prepare uniform Y2O3-Eu hollow spheres, Cryst. Growth. Des. 9 (2009) 301-307.
-
[15]
[15] R. Si, Y.W. Zhang, L.P. You, C.H. Yan, Rare-earth oxide nanopolyhedra, nanoplates, and nanodisks, Angew. Chem. Int. Ed. Engl. 117 (2005) 3320-3324.
-
[16]
[16] S. Huang, J. Xu, Z. Zhang, et al., Rapid, morphologically controllable, large-scale synthesis of uniform Y(OH)3 and tunable luminescent properties of Y2O3:Yb3+/3+(Ln=Er, Tm and Ho), J. Mater. Chem. 22 (2012) 16136-16144.
-
[17]
[17] R.V. Mangalaraja, J. Mouzon, P. Hedström, et al., Combustion synthesis of Y2O3 and Yb-Y2O3, J. Mater. Proc. Technol. 208 (2008) 415-422.
-
[18]
[18] V.V. Rajasekharan, D.A. Buttry, Electrochemical synthesis of yttrium oxide nanotubes, Chem. Mater. 18 (2006) 4541-4543.
-
[19]
[19] G. Mialon, M. Gohin, T. Gacoin, J.P. Boilot, High temperature strategy for oxide nanoparticle synthesis, ACS Nano 2 (2008) 2505-2512.
-
[20]
[20] X. Qin, T. Yokomori, Y. Ju, Flame synthesis and characterization of rare-earth (Er3+, Ho3+, and Tm3+) doped upconversion nanophosphors, Appl. Phys. Lett. 90 (2007) 073104.
-
[21]
[21] D.H.M. Buchold, C. Feldmann, Microemulsion approach to non-agglomerated and crystalline nanomaterials, Adv. Funct. Mater. 18 (2008) 1002-1011.
-
[22]
[22] Z. Huo, C. Chen, Y. Li, Self-assembly of uniform hexagonal yttrium phosphate nanocrystals, Chem. Commun. (Camb.) (2006) 3522-3524.
-
[23]
[23] S. Yin, S. Akita, M. Shinozaki, R. Li, T. Sato, Synthesis and morphological control of rare earth oxide nanoparticles by solvothermal reaction, J. Mater. Sci. 43 (2007) 2234-2239.
-
[24]
[24] A.M. Petrosyan, V.V. Ghazaryan, Vibrational spectra of L-lysine monohydrochloride dihydrate and its two anhydrous forms, J. Mol. Struct. 917 (2009) 56-62.
-
[25]
[25] T. Gougousi, Z. Chen, Deposition of yttrium oxide thin films in supercritical carbon dioxide, Thin Solid Films 516 (2008) 6197-6204.
-
[26]
[26] Y.F. Lin, J.H. Chen, S.H. Hsu, T.W. Chung, Hydrothermal synthesis of Lewis acid Y2O3 cubes and flowers for the removal of phospholipids from soybean oil, CrystEngComm 15 (2013) 6506-6510.
-
[27]
[27] W.W. Cai, H. Huang, X.Z. Guo, A facile one-step route to synthesize titania hollow microspheres with incontinuous multicavities, Chin. Chem. Lett. 25 (2014) 441-446.
-
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