Citation: Mian HR Mahmood, Ze-Yu Liu, Hai-Yang Liu, Huai-Bo Zou, C. -K. Chang. Improved synthesis of sterically encumbered multibrominated corroles[J]. Chinese Chemical Letters, ;2014, 25(10): 1349-1353. doi: 10.1016/j.cclet.2014.04.016 shu

Improved synthesis of sterically encumbered multibrominated corroles

1.
a Department of Chemistry, South China University of Technology, Guangzhou 510641, China;
2.
b Department of Chemistry, University of Education, Lahore 54770, Pakistan;
c Department of Chemistry, Michigan State University, E.
c Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

Corresponding author: Hai-Yang Liu,
Received Date: 10 March 2014
Available Online: 14 April 2014
Fund Project:

Efficient and easily reproducible synthesis of sterically hindered multibrominated corroles is achieved via dipyrromethane-aldehyde condensation reaction in good yields. Boron trifluoride dietherate (BF₃·Et₂O) is found to be the effective catalyst for cyclization reaction, giving corrole as the major product.
- Brominated corrole,
- Porphyrin,
- Dipyrromethane,
- Boron trifluoride dietherate
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