Citation: An-Qi Ju, Meng-Juan Li, Miao Luo, Ming-Qiao Ge. Poly(acrylonitrile-co-3-aminocarbonyl-3-butenoic acid methyl ester)：A better precursor material for carbon fi ber than acrylonitrile terpolymer[J]. Chinese Chemical Letters, ;2014, 25(9): 1275-1278. doi: 10.1016/j.cclet.2014.03.009 shu

Poly(acrylonitrile-co-3-aminocarbonyl-3-butenoic acid methyl ester)：A better precursor material for carbon fi ber than acrylonitrile terpolymer

An-Qi Ju ^a,b,, ,
Meng-Juan Li ^a ,
Miao Luo ^c ,
Ming-Qiao Ge ^a

1.
a Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, China;
2.
b College of Textile & Clothing, Jiangnan University, Wuxi 214122, China;
3.
c School of Pharmacy, East China University of Science and Technology, Shanghai 201620, China

Corresponding author: An-Qi Ju,
Received Date: 4 December 2013
Available Online: 28 February 2014
Fund Project: Financial support of this work from Important National Research Program "863" (No. 2012AA030313-1) (No. 2012AA030313-1) Undergraduate Innovation Project (No. 1065210232130740) (No. 1065210232130740)The Fundamental Research Funds for the Central Universities (No. JUSRP11450) were gratefully acknowledged. (No. JUSRP11450)

In order to improve the stabilization and spinnability of polyacrylonitrile, a bifunctional comonomer containing both ester and amide groups was synthesized to prepare poly(acrylonitrile-co-3-aminocarbonyl-3-butenoic acid methyl ester) [P(AN-co-ABM)] copolymers used as the carbon fiber precursor instead of poly(acrylonitrile-acrylamide-methyl acrylate) [P(AN-AM-MA)] terpolymer. The differential scanning calorimetry and thermogravimetry results show that the stabilization of P(AN-co-ABM) have been remarkably improved by ABM compared with P(AN-AM-MA) terpolymer, such as lower initiation temperature, broadened exothermic peak and smaller activation energy. Moreover, the spinnability of P(AN-co-ABM) is also improved by ABM due to the lubrication of ester groups in ABM. This study clearly shows that P(AN-co-ABM) copolymer is a better material for use as a carbon fiber precursor than P(AN-AM-MA) terpolymer.
- Polymerization,
- Stabilization,
- DSC,
- Spinnability,
- Carbon fiber
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