Citation:
Peng-Fei Shi, Qin Jiang, Hai-Chao Duan, Da-Qi Wang. Synthesis, characterization and cytotoxicity of fluorescent organotin complexes of terpyridine derivatives[J]. Chinese Chemical Letters,
;2014, 25(4): 586-588.
doi:
10.1016/j.cclet.2014.01.049
-
Five organotin complexes of terpyridine derivatives were synthesized and characterized. The mononuclear Sn(Ⅳ) complexes were six-coordinated adopting a distorted octahedral coordination geometry. A brief outline of the fluorescence spectra and the in vitro cytotoxicity of the Sn(Ⅳ) complexes have been given.
-
Keywords:
- Organotin,
- Terpyridine,
- Antitumor
-
-
-
[1]
[1] N. Mala, K.S. Pramendra, Chemistry and applications of organotin(Ⅳ) complexes of Schiff bases, Dalton Trans. 40 (2011) 7077-7121.
-
[2]
[2] U.S. Schubert, A. Winter, G.R. Newkome, Optoelectronic and Life Science Applications, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 2011.
-
[3]
[3] D.V. Naik, W.R. Scheidt, Crystal and molecular structure of dimethyldiisothiocyanato( terpyridyl)tin (Ⅳ), Inorg. Chem. 12 (1973) 272-276.
-
[4]
[4] F.W.B. Einstein, B.R. Penfold, The crystal structure of a compound containing tin(Ⅳ) inboth5-fold and6-fold co-ordination:[(CH3)2SnCl,terpyridyl]+[(CH3)2SnCl3] , J. Chem. Soc. A (1968) 3019-3024.
-
[5]
[5] E. Najafi, M.M. Amini, S.W. Ng, Dimethyl(4'-pyridyl-2,2':6',2''-terpyridine k3N1N1', N1'')bis(thiocyanato-kN)-tin(Ⅳ), Acta Cryst. Sec. E 67 (2011) m211.
-
[6]
[6] N.W.G. Debye, E. Rosenberg, J.J. Zuckerman, Tin-119m Mössbauer study of fiveand six-coordinated organotin(Ⅳ) ions, J. Am. Chem. Soc. 90 (1968) 3234-3236.
-
[7]
[7] S.H. Li, F.R. Chen, Y.F. Zhou, et al., Enhanced fluorescence sensing of hydroxylated organotins by a boronic acid-linked Schiff base, Chem. Commun. (2009) 4179- 4181.
-
[8]
[8] O. Johansson, M. Borgstro¨m, R. Lomoth, et al., Electron donor-acceptor dyads based on ruthenium(Ⅱ) bipyridine and terpyridine complexes bound to naphthalenediimide, Inorg. Chem. 42 (2003) 2908-2918.
-
[9]
[9] P.F. Shi, Q. Jiang, Preparation of water-soluble terpyridyl fluorescent compound, CN 102584686 A.
-
[10]
[10] M.X. Lin, X.Y. Wang, J.H. Zhu, et al., Cellular and biomolecular responses of human ovarian cancer cells to cytostatic dinuclear platinum(Ⅱ) complexes, Apoptosis 16 (2011) 288-300.
-
[1]
-
-
-
[1]
Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
-
[2]
Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
-
[3]
Jing Zhang , Charles Wang , Yaoyao Zhang , Haining Xia , Yujuan Wang , Kun Ma , Junfeng Wang . Application of magnetotactic bacteria as engineering microrobots: Higher delivery efficiency of antitumor medicine. Chinese Chemical Letters, 2024, 35(10): 109420-. doi: 10.1016/j.cclet.2023.109420
-
[4]
Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
-
[5]
Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348
-
[6]
Jin Wang , Xiaoyan Pan , Junyu Zhang , Qingqing Zhang , Yanchen Li , Weiwei Guo , Jie Zhang . Active molecule-based theranostic agents for tumor vasculature normalization and antitumor efficacy. Chinese Chemical Letters, 2024, 35(8): 109187-. doi: 10.1016/j.cclet.2023.109187
-
[7]
Zhaomin Tang , Qian He , Jianren Zhou , Shuang Yan , Li Jiang , Yudong Wang , Chenxing Yao , Huangzhao Wei , Keda Yang , Jiajia Wang . Active-transporting of charge-reversal Cu(Ⅱ)-doped mesoporous silica nanoagents for antitumor chemo/chemodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109742-. doi: 10.1016/j.cclet.2024.109742
-
[8]
Hong-Tao Ji , Yu-Han Lu , Yan-Ting Liu , Yu-Lin Huang , Jiang-Feng Tian , Feng Liu , Yan-Yan Zeng , Hai-Yan Yang , Yong-Hong Zhang , Wei-Min He . Nd@C3N4-photoredox/chlorine dual catalyzed synthesis and evaluation of antitumor activities of 4-alkylated sulfonyl ketimines. Chinese Chemical Letters, 2025, 36(2): 110568-. doi: 10.1016/j.cclet.2024.110568
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(642)
- HTML views(2)