Citation:
Haitham Mohammad Abdelaal. Fabrication of hollow silica microspheres utilizing a hydrothermal approach[J]. Chinese Chemical Letters,
;2014, 25(4): 627-629.
doi:
10.1016/j.cclet.2014.01.043
-
Hollow silica microspheres (HSMSs) have been successfully fabricated via a facile hydrothermal route using D-glucose as the sacrificial template and sodium silicate powder as the silica precursor. The resulting silica hollow particles were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and infrared spectroscopy (IR). The surface area was determined using the BET method. SEM and TEM images exhibited micro-sized silica hollow particles with a size of ~1.5 μm.
-
Keywords:
- Silica,
- Hollow materials,
- Glucose,
- Hydrothermal method
-
-
-
[1]
[1] X. Wang, Y. Yang, Y. Ma, J.N. Yao, Controlled synthesis of multi-shelled transition metal oxide hollow structures through one-pot solution route, Chin. Chem. Lett. 24 (2013) 1-6.
-
[2]
[2] C. Hu, Y. Xu, S. Duo, et al., Preparation of inorganic hollow spheres based on different methods, J. Chin. Chem. Soc. 57 (2010) 1091-1098.
-
[3]
[3] C. Fowler, D. Khushalani, S. Mann, Interfacial synthesis of hollow microspheres of mesostructured silica, Chem. Commun. (2001) 2028-2029.
-
[4]
[4] J. Jang, K. Lee, Facile fabrication of hollow polystyrene nanocapsules by microemulsion polymerization, Chem. Commun. (2002) 1098-1099.
-
[5]
[5] I. Tissot, J. Reymond, F. Lefebvre, E. Bourgeat-Lami, SiOH functionalized polystyrene latexex: a step toward the synthesis of hollow silica nanoparticles, Chem. Mater. 14 (2002) 1325-1331.
-
[6]
[6] O. Emmerich, N. Hugenberg, M. Schmidt, et al., Molecular boxes based on hollow organosilicon micronetworks, Adv. Mater. 11 (1999) 1299-1303.
-
[7]
[7] X. Lv, L. Wang, G. Li, et al., Preparation and characterization of optically functional hollow sphere hybrid materials by surface-initiated RATRP and "Click" chemistry, Chin. Chem. Lett. 24 (2013) 335-337.
-
[8]
[8] C. Graf, A. van Blaaderen, Metallodielectric colloidal core-shell particles for photonic applications, Langmuir 18 (2002) 524-534.
-
[9]
[9] X.M. Sun, Y.D. Li, Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles, Angew. Chem. Int. Ed. 43 (2004) 597-601.
-
[10]
[10] W.H. Shen, Y.F. Zhu, X.P. Dong, J.L. Gu, J.L. Shi, A new strategy to synthesize TiO2 hollow spheres using carbon spheres as template, Chem. Lett. 34 (2005) 840-841.
-
[11]
[11] X.L. Li, T.J. Lou, X.M. Sun, Y.D. Li, Highly sensitive WO3 hollow-sphere gas sensors, Inorg. Chem. 43 (2004) 5442-5449.
-
[12]
[12] H.Y. Wang, R.J. Wang, X.M. Sun, R.X. Yan, Y.D. Li, Synthesis of red-luminescent Eu3+-doped lanthanides compounds hollow spheres Mater, Res. Bull. 40 (2005) 911-919.
-
[13]
[13] M. Sevilla, A.B. Fuertes, The production of carbon materials by hydrothermal carbonization of cellulose, Carbon 47 (2009) 2281-2289.
-
[14]
[14] L. Sierra, B. Lopez, J.L. Guth, Preparation of mesoporous silica particles with controlled morphology from sodium silicate solutions and a non-ionic surfactant at pH values between 2 and 6, Microporous Mesoporous Mater. 39 (2000) 519-527.
-
[15]
[15] J. Martinez, S. Sanchez, G. Zarzosa, F. Ruiz, Y. Chumakov, Rietveld refinement of amorphous SiO2 prepared via sol-gel method, Mater. Lett. 60 (2006) 3526-3529.
-
[16]
[16] L.H. Little, Infrared Spectra of Adsorbed Species, Academic Press, New York, 1966.
-
[17]
[17] S. Ryu, M. Tomozawa, Fictive temperature measurement of amorphous SiO2 films by IR method, J. Non-Cryst. Solids 352 (2006) 3929-3935.
-
[18]
[18] K.S.W. Sing, D.H. Everett, R.A.W. Haul, et al., Reporting physisorption data for gas/ solid system with special reference to the determination of surface area and porosity, Pure Appl. Chem. 57 (1985) 603-619.
-
[19]
[19] E.P. Barrett, L.G. Joyner, P.P. Halenda, The determination of pore volume and area distribution in porous substances. I. Computations from nitrogen isotherms, J. Am. Chem. Soc. 73 (1951) 373-380.
-
[1]
-
-
-
[1]
Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
-
[2]
Jiaxuan Wang , Tonghe Liu , Bingxiang Wang , Ziwei Li , Yuzhong Niu , Hou Chen , Ying Zhang . Synthesis of polyhydroxyl-capped PAMAM dendrimer/silica composites for the adsorption of aqueous Hg(II) and Ag(I). Chinese Chemical Letters, 2024, 35(12): 109900-. doi: 10.1016/j.cclet.2024.109900
-
[3]
Junqing Wu , Yiyang Zhang , Qingqing Hong , Hui Yang , Lifeng Zhang , Ming Zhang , Lei Yu . Organometallic modification of silica with europium endowing the fluorescence properties: The key technique for numerical quality monitoring. Chinese Chemical Letters, 2025, 36(4): 110165-. doi: 10.1016/j.cclet.2024.110165
-
[4]
Jiaxu Wang , Jinxie Zhang , Xiuping Wang , Jingying Wang , Lina Chen , Jiahui Cao , Wei Cao , Siyu Liang , Ping Luan , Ke Zheng , Xiao-Kun Ouyang , Li Gao , Xiaowen Ou , Fan Zhang , Meitong Ou , Lin Mei . CaCO3-coated hollow mesoporous silica nanoparticles for pH-responsive fungicides release. Chinese Chemical Letters, 2024, 35(12): 109697-. doi: 10.1016/j.cclet.2024.109697
-
[5]
Jiahui Li , Qiao Shi , Ying Xue , Mingde Zheng , Long Liu , Tuoyu Geng , Daoqing Gong , Minmeng Zhao . The effects of in ovo feeding of selenized glucose on liver selenium concentration and antioxidant capacity in neonatal broilers. Chinese Chemical Letters, 2024, 35(6): 109239-. doi: 10.1016/j.cclet.2023.109239
-
[6]
Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012
-
[7]
Shengfei Dong , Ziyu Liu , Xiaoyi Yang . Hydrothermal liquefaction of biomass for jet fuel precursors: A review. Chinese Chemical Letters, 2024, 35(8): 109142-. doi: 10.1016/j.cclet.2023.109142
-
[8]
Kezuo Di , Jie Wei , Lijun Ding , Zhiying Shao , Junling Sha , Xilong Zhou , Huadong Heng , Xujing Feng , Kun Wang . A wearable sensor device based on screen-printed chip with biofuel cell-driven electrochromic display for noninvasive monitoring of glucose concentration. Chinese Chemical Letters, 2025, 36(2): 109911-. doi: 10.1016/j.cclet.2024.109911
-
[9]
Zhaomin Tang , Qian He , Jianren Zhou , Shuang Yan , Li Jiang , Yudong Wang , Chenxing Yao , Huangzhao Wei , Keda Yang , Jiajia Wang . Active-transporting of charge-reversal Cu(Ⅱ)-doped mesoporous silica nanoagents for antitumor chemo/chemodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109742-. doi: 10.1016/j.cclet.2024.109742
-
[10]
Jichun Li , Zhengren Wang , Yu Deng , Hongxiu Yu , Yonghui Deng , Xiaowei Cheng , Kaiping Yuan . Construction of mesoporous silica-implanted tungsten oxides for selective acetone gas sensing. Chinese Chemical Letters, 2024, 35(11): 110111-. doi: 10.1016/j.cclet.2024.110111
-
[11]
Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
-
[12]
Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
-
[13]
Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
-
[14]
Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
-
[15]
Zhiwei Zhong , Yanbin Huang , Wantai Yang . A simple photochemical method for surface fluorination using perfluoroketones. Chinese Chemical Letters, 2024, 35(5): 109339-. doi: 10.1016/j.cclet.2023.109339
-
[16]
Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
-
[17]
Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
-
[18]
Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
-
[19]
Wenxuan Yang , Long Shang , Xiaomeng Liu , Sihan Zhang , Haixia Li , Zhenhua Yan , Jun Chen . Ultrafast synthesis of nanocrystalline spinel oxides by Joule-heating method. Chinese Chemical Letters, 2024, 35(11): 109501-. doi: 10.1016/j.cclet.2024.109501
-
[20]
Chen Chen , Jinzhou Zheng , Chaoqin Chu , Qinkun Xiao , Chaozheng He , Xi Fu . An effective method for generating crystal structures based on the variational autoencoder and the diffusion model. Chinese Chemical Letters, 2025, 36(4): 109739-. doi: 10.1016/j.cclet.2024.109739
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(626)
- HTML views(2)