Citation: Abdullah G. Al-Sehemi, Ahmad Irfan, Abdullah M. Asiri. Red and yellow color aspects of compound 3-dicyclopropylmethylene-5-dicyanomethylene-4-diphenylmethylenetetrahydrofuran-2-one：Chromism effect[J]. Chinese Chemical Letters, ;2014, 25(4): 609-612. doi: 10.1016/j.cclet.2014.01.016 shu

Red and yellow color aspects of compound 3-dicyclopropylmethylene-5-dicyanomethylene-4-diphenylmethylenetetrahydrofuran-2-one：Chromism effect

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a Department of Chemistry, Faculty of Science, King Khalid University, Abha 61413, Saudi Arabia;
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b Unit of Science and Technology, Faculty of Science, King Khalid University, Abha 61413, Saudi Arabia;
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c Center of Excellence for Advanced Materials Research, King Khalid University, Abha 61413, Saudi Arabia;
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d Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia;
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e Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21589, Saudi Arabia

Corresponding author: Ahmad Irfan,
Received Date: 11 July 2013
Available Online: 26 November 2013

The title compound exists as yellow (1Y) and red (1R) crystals, but both gave red solutions. The intermolecular interactions between the CN parts of the crystals in 1Y are very weak. By the mechanical crushing as well as in solution 1Y again becomes red due to the absence of intermolecular interactions. We explain this color behavior by crystallochromism and solvation chromism.
- Intermolecular interactions,
- Crystallochromism,
- Solvation chromism
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