Citation: Zi-Lan Feng, Yuan-Yuan Yao, Jing-Kun Xu, Long Zhang, Zi-Fei Wang, Yang-Ping Wen. One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid[J]. Chinese Chemical Letters, ;2014, 25(4): 511-516. doi: 10.1016/j.cclet.2014.01.004 shu

One-step co-electrodeposition of graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) film and its electrochemical studies of indole-3-acetic acid

Zi-Lan Feng ^a,b ,
Yuan-Yuan Yao ^a ,
Jing-Kun Xu ^a,, ,
Long Zhang ^a ,
Zi-Fei Wang ^a,b ,
Yang-Ping Wen ^b,,

1.
a Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China;
2.
b College of Science, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: Jing-Kun Xu, Yang-Ping Wen,
Received Date: 24 October 2013
Available Online: 17 December 2013
Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 51263010, 51272096) (Nos. 51263010, 51272096) Jiangxi Provincial Department of Education (No. GJJ11590) (No. GJJ11590)

A novel graphene oxide (GO) doped poly(hydroxymethylated-3,4-ethylenedioxythiophene) (PEDOTM) film has been achieved via one-step co-electrodeposition and utilized for electrochemical studies of indole-3-acetic acid (IAA). The incorporation of GO into PEDOTM film facilitated the electrocatalytic activity and exhibited a favorable interaction between the PEDOTM/GO film and the phytohormone during the oxidation of IAA. Under optimized conditions, differential pulse voltammetry and square wave voltammetry were used for the quantitative analysis of IAA, respectively, each exhibiting a wide linearity range from 0.6 μmol L^-1 to 10 μmol L^-1 and 0.05 μmol L^-1 to 40 μmol L^-1, good sensitivity with a low detection limit of 0.087 μmol L^-1 and 0.033 μmol L^-1, respectively, as well as good stability. With the notable advantages of a green, sensitive method, expeditious response and facile operation, the as-prepared PEDOTM/GO organic-inorganic composite film provides a promising platform for electrochemical studies of IAA.
- Co-electrodeposition,
- EDOT derivatives,
- Graphene oxide,
- Indole-3-acetic acid
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