Citation: Mohammad Ali Taher, Zahra Daliri, Hamid Fazelirad. Simultaneous extraction and preconcentration of copper, silver and palladium with modified alumina and their determination by electrothermal atomic absorption spectrometry[J]. Chinese Chemical Letters, ;2014, 25(4): 649-654. doi: 10.1016/j.cclet.2013.12.025 shu

Simultaneous extraction and preconcentration of copper, silver and palladium with modified alumina and their determination by electrothermal atomic absorption spectrometry

1.
a Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, Iran;
2.
b Department of Polymer, Science and Research Branch, Islamic Azad University, Yazd, Iran;
c Young Researchers Society, Shahid Bahonar University of Kerman, P.
c Young Researchers Society, Shahid Bahonar University of Kerman, P.O. Box 76175-133, Kerman, Iran

Corresponding author: Hamid Fazelirad,
Received Date: 27 November 2013
Available Online: 31 December 2013

In the present work, an easy solid phase extraction method using alumina modified with polyethylenimine as a new adsorbent was applied to the simultaneous extraction of copper, silver, and palladium ions prior to their determination with electrothermal atomic absorption spectrometry. The analytical procedure involved the complex formation of these cations with polyethylenimine as a chelating agent in buffer media of pH 7.0. Under the optimum conditions, a preconcentration factor of 200, 150, and 200, precision of ±5.4%, ±4.7%, and ±5.2% and linear calibration ranges of 15.0-140, 4.0-93, and 7.5-125 ng/L (in original solution) for Cu, Ag, and Pd were obtained, respectively. Also detection limits of 3.9, 1.1, and 2.0 ng/L were obtained for Cu, Ag, and Pd, respectively. The proposed method was applied to the determination of copper, silver, and palladium in some real samples with satisfactory results.
- Polyethylenimine,
- Solid phase extraction,
- Copper,
- Silver,
- Palladium,
- Electrothermal atomic absorption,
- spectrometry
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