Citation: Wen Zheng Gao, Xiang Gao Li, Shi Rong Wang, Hai Jun Lv. Synthesis and properties of novel hole-transporting materials with triphenylamine units[J]. Chinese Chemical Letters, ;2012, 23(2): 141-144. doi: 10.1016/j.cclet.2011.11.018 shu

Synthesis and properties of novel hole-transporting materials with triphenylamine units

a School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
b College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology Shijiazhuang 050018, China

Received Date: 12 July 2011

Fund Project: The authors gratefully thank the National Natural Science Foundation of China (No. 21176180) and Research Fund for the Doctoral Program of Higher Education of China (No. 20100032110021) for the financial support.

Two novel organic hole-transporting materials have been synthesized by combination of triphenylamines (TPA) via π-conjugated bonds using Wittig reaction. The structures were characterized by NMR, FT-IR and HRMS. The optical, electrochemical and thermal properties of the materials were studied in detail. The results show that these two compounds have blue emission, proper HOMO levels and high thermal stability. Furthermore, a quantum chemical calculation on electron distribution of the two compounds was performed, which suggests the current synthesized materials would be promising candidates for hole-transporting materials.
- Wittig reaction,
- Triphenylamine,
- Hole-transporting materials,
- Quantum chemical calculation
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